6382-98-5Relevant academic research and scientific papers
Syntheses of penta-O-benzyl-myo-inositols, O-β-L-arabinosyl-(1 → 2)sn-myo-inositol, O-α-D-galactosyl-(1 → 3)-sn-myo-inositol, and O-α-D-galactosyl-(1 → 6)-O-α-D-galactosyl-(1 → 3)-sn-myo-inositol
Koto,Hirooka,Yoshida,Takenaka,Nagamitsu,Sakurai,Zen,Yago,Tomonaga
, p. 2521 - 2529 (2007/10/03)
Two-step conversions of myo-inositol into (±)-2,3,4,5,6- and 1,3,4,5,6-penta-O-benzyl-myo-inositols are described. Starting from these monohydroxy derivatives of myo-inositol, O-β-L-arabinopyranosyl-(1→2)-sn-myo-inositol from Japanese green tea, Camellia sinensis, and O-α-D-galactopyranosyl-(1→3)-sn-myo-inositol (galactinol) as well as its homolog, O-α-D-galactopyranosyl-(1→6(II))-galactinol, were synthesized by way of the in situ activating glycosylation procedure.
Concerning the reactivities of the C-1, C-2 and C-6 hydroxy groups of myo-inositol
Anilkumar, Gopinadhan Nair,Jia, Zhaozhong J.,Kraehmer, Ralf,Fraser-Reid, Bert
, p. 3591 - 3596 (2007/10/03)
Regioselectivities in the reactions of the three contiguous free hydroxy groups at C-6, C-1, and C-2 of 3,4,5-tri-O-benzyl-D-myo-inositol have been examined. Stannylene activation permits selective alkylation and esterification at C-1; however, acyl migra
Practical synthesis of a differentially protected myo-inositol
Kornienko, Alexander,Turner, David I.,Jaworek, Christine H.,D'Alarcao, Marc
, p. 2783 - 2786 (2007/10/03)
An enantiospecific synthesis of 3,4,5-tri-O-benzyl-6-O- triisopropylsilyl-D-myo-inositol from D-xylose is reported. The synthesis features a diastereofacially selective SmI2-promoted pinacol cyclization.
Synthesis of novel vitamin C phosphodiesters: Stability and antioxidant activity
Morisaki, Kazuo,Ozaki, Shoichiro
, p. 123 - 138 (2007/10/03)
A novel series of hybrid L-ascorbic acid (vitamin C) phosphodiesters linked at the C-2 hydroxyl group with other biologically active substances, namely myo-inositol, arbutin, 4-hydroxy-L-proline, and glycolic acid were synthesized, and their thermal stability and reducing activity against free radicals were estimated in vitro. All of the phosphodiesters exhibited high thermal stabilities; however, their antioxidant activities in vitro were generally lower than that of vitamin C.
Synthesis of -Labelled and Unlabelled 2-Deoxy-2-fluoro-myo-inositol and 1-Deoxy-1-fluoro-scyllo-inositol for Use in Studies of the Phosphoinositide Cycle
Lowe, Gordon,McPhee, Fiona
, p. 1249 - 1253 (2007/10/02)
2-Deoxy-2-fluoro-myo-inositol and 1-deoxy-1-fluoro-scyllo-inositol have been synthesized in their unlabelled and tritiated forms in order to study their potential as inhibitors of the phosphoinositide cycle.
