63832-88-2Relevant academic research and scientific papers
INTERACTION OF THIOESTERS OF P(III) WITH OXYGEN
Burilov, A. R.,Drozdova, Ya. A.,Pudovik, M. A.,Pudovik, A. N.
, p. 1885 - 1890 (2007/10/02)
The compounds O,O-diethyl- and O,O-diisopropyl-S-benzylthiophosphite, 2-benzylthio-4,5-benzo-1,3,2-dioxaphospholane, diphenyl-S-benzylthiophosphinite, and S,S-dibenzylphenyldithiophosphonite were obtained.It was found that the thiophosphites enter into is
INTERACTION OF DISULFIDES AND SULFENYLCHLORIDES WITH C-N,N-DIALKYLAMINOSUBSTITUTED PHOSPHAALKENES
Ionkin, A. S.,Nikolaeva, N. V.,Nekhoroshkov, V. M.,Efremov, Yu. Ya.,Arbuzov, B. A.
, p. 361 - 365 (2007/10/02)
Interaction of dialkyl disulfides with C-N,N-dimethylaminomethylene-P-phenylphosphine 1a results in the complete cleavage of the P=C double bond and formation of S,S-dialkylphenyldithiophosphonites.Ethyl sulfenylchloride undergoes dehydrochlorination by 1a, while phenyl sulfenylchloride cleaves the P=C bond in C-N,N-dialkylaminosubstituted phosphaalkenes with the predominant formation of either PhP(SPh)2 6 or PhP(SPh)Cl 7 depending on the phosphaalkene used and reaction conditions. Key words: C-(N,N-dialkylamino) substituted phosphaalkenes; disulfides; sulfenylchlorides.
