63901-87-1

Basic information

• Product Name: Furan, tetrahydro-2-(4-methylphenoxy)-
• CAS NO: 63901-87-1
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 63901-87-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Furan, tetrahydro-2-(4-methylphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Furan, tetrahydro-2-(4-methylphenoxy)-(63901-87-1)
• EPA Substance Registry System: Furan, tetrahydro-2-(4-methylphenoxy)-(63901-87-1)

Safety Data

• Hazardous Substances Data: 63901-87-1(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 106-44-5 p-cresol 
• 13481-09-9 2-(4-methylphenoxy)tetrahydro-2H-pyran 
• 1191-99-7 2,3-dihydro-2H-furan 

Relevant articles and documents

CuBr2-promoted tetrahydrofuranylation of alcohols and 1,3-dione

A method for the CuBr2-promoted tetrahydrofuranylation of alcohols and 1,3-dione has been developed. A variety of different alcohols were efficiently converted into the corresponding 2-tetrahydrofuran ethers in the presence of CuBr2. It is noteworthy that this protocol also successfully converted 1,3-diphenyl-1,3-dione into the corresponding 2-tetrahydrofuran derivative in good yield. Georg Thieme Verlag Stuttgart - New York.

MIXED AROMATIC-ALIPHATIC ACETALS; THEIR PREPARATION, (1)H AND (13)C-NMR SPECTRA AND HYDROGENOLYSIS BY ETHEREAL SOLUTION OF CHLOROALANE

The corresponding p-X-phenylisobutyl acetals of acetaldehyde (I), 2-(p-X-phenoxy)tetrahydropyrans (II), 2-(p-X-phenoxy)tetrahydrofurans (III), and cyclohexyl(p-X-phenyl)acetals of acetaldehyde (IV) were prepared by addition of p-X-substituted phenols to isobutyl vinyl ether, 2,3-dihydro-4H-pyran, 2,3-dihydrofuran, and cyclohexyl vinyl ether, respectively.The structures of acetals I-IV were confirmed by their (1)H and (13)C-NMR spectra.Diastereotopic protons of the methylene and geminal methyl groups are anisochronous in the (1)H-NMR spectra of acetals I. (13)C-NMR spectra of acetals IV demonstrate anisochronous behaviour of cyclohexane ring diastereotopic carbon atoms.The constants ?p+ for several groups calculated using (13)C-NMR spectra are: 1-isobutoxy-1-ethoxy- (-0.58), 2-tetrahydrofuryloxy- (-0.59), and 1-cyclohexyloxy-(1-ethoxy) (-0.57).Experimental relative rate constants of hydrogenolysis of acetals I and II by ethereal solution of chloroalane yield best correlations with ?p+ constants of the substituent X, providing the values ρ= -1.09 for compounds of the series I and II, respectively.The importance of these results for finding the rate determining step of the studied reaction is discussed.