63913-42-8

Basic information

• Product Name: 3-Penten-2-one, 4-(4-morpholinyl)-, (E)-
• CAS NO: 63913-42-8
• Molecular Formula: C9H15NO2
• Molecular Weight: 169.224
• Mol File: 63913-42-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Penten-2-one, 4-(4-morpholinyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Penten-2-one, 4-(4-morpholinyl)-, (E)-(63913-42-8)
• EPA Substance Registry System: 3-Penten-2-one, 4-(4-morpholinyl)-, (E)-(63913-42-8)

Safety Data

• Hazardous Substances Data: 63913-42-8(Hazardous Substances Data)

Upstream product

• 14212-87-4 1,1-bis(N-morpholinyl)ethylene 
• 123-54-6 acetylacetone 

Downstream Products

• 1696-20-4 4-acetylmorpholine 
• 127-17-3 2-oxo-propionic acid 
• 2258-42-6 formyl acetic anhydride 
• 256340-88-2 5-acetyl-3-cyano-4-isobutyl-6-methyl-3,4-dihydropyridine-2(1H)-thione 
• 769-28-8 3-Cyano-4,6-dimethyl-2(1H)-pyridon 
• 53475-39-1 3-benzoyl-4,6-dimethyl-2(1H)-pyridone 
• 3613-70-5 2-benzylthio-4,6-dimethylpyrimidine 
• 10024-89-2 morpholin hydrochloride 
• 14164-34-2 4,6-dimethyl-2-phenylpyrimidine 
• 54585-47-6 4,6-Dimethyl-2-thioxo-1,2-dihydro-pyridine-3-carbonitrile 
• 112629-72-8 2-Allylsulfanyl-4,6-dimethyl-nicotinonitrile 

Relevant articles and documents

Condensation reactions of 1.1-dimorpholinoethene and of 1,1-dipiperidinoethene with carbon acids

1,1-Dimorpholinoethene and 1,1-dipiperidinoethene condense with such compounds as malonitrile, ethyl cyanoacetate, cyanoacetamide, and diethyl malonate to give the corresponding β,β-disubstituted enamine, a molecule of morpholine or piperidine being eliminated in the process.Similar reactions with acetylacetone and ethyl acetoacetate proceed with loss of the acetyl group to give the β-enamine. 1,1-Dipiperidinoethene and nitromethane give the β-nitroenamine.Secondary process of either hydrolysis or further Michael addition and elimination are noted in condensations of 1,1-dimorpholinoethene or 1,1-dipiperidinoethene with cyanoacetamide under more basic conditions. 1,1-Dipiperidinoethene is arylated at the 2-position by 2,4-dinitrochlorobenzene.