63969-83-5

Basic information

• Product Name: methyl 2-(2-formylphenyl)acetate
• Synonyms: methyl 2-(2-formylphenyl)acetate;Methyl 2-(2-formylphenyl)
• CAS NO: 63969-83-5
• Molecular Formula: C₁₀H₁₀O₃
• Molecular Weight: 178.186
• Mol File: 63969-83-5.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 273.9 °C at 760 mmHg
• Flash Point: 117.5 °C
• Appearance: /
• Density: 1.157
• Vapor Pressure: 0.00559mmHg at 25°C
• Refractive Index: 1.549
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility: Chloroform (Slightly)
• Stability: Air Sensitive
• CAS DataBase Reference: methyl 2-(2-formylphenyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(2-formylphenyl)acetate(63969-83-5)
• EPA Substance Registry System: methyl 2-(2-formylphenyl)acetate(63969-83-5)

Safety Data

• Hazardous Substances Data: 63969-83-5(Hazardous Substances Data)

Usage

General Description

Methyl 2-(2-formylphenyl)acetate is a chemical compound with the molecular formula C11H12O3. It is an organic ester that is commonly used in the fragrance and flavor industry for its sweet and floral aroma. methyl 2-(2-formylphenyl)acetate is often found in various cosmetic and personal care products, as well as in food and beverage flavorings. Methyl 2-(2-formylphenyl)acetate can be synthesized from the reaction of 2-formylphenylboronic acid with methyl acetate in the presence of a palladium catalyst. It is important to handle this compound with care and to follow proper safety precautions when working with it due to its potential health hazards.

InChI:InChI=1/C10H10O3/c1-13-10(12)6-8-4-2-3-5-9(8)7-11/h2-5,7H,6H2,1H3

Upstream product

• 1723-55-3 ortho-formylphenylacetic acid 
• 13737-37-6 methyl 2-[2-(bromomethyl)phenyl]acetate 
• 644-36-0 o-methylphenylacetic acid 
• 67-56-1 methanol 
• 29810-10-4 methyl α-(N,N-dimethylamino)phenylacetate 
• 1358418-45-7 methyl α-(N-cyanomethyl-N-methylamino)phenylacetate 
• 1358418-47-9 2-(methoxycarbonylmethyl)-α-(dimethylamino)phenylacetonitrile 
• 1358418-57-1 N-cyanomethyl-N,N-dimethyl-N-(α-methoxycarbonylbenzyl)ammonium trifluoromethanesulfonate 
• 1358418-55-9 N-cyanomethyl-N,N-dimethyl-N-(α-methoxycarbonylbenzyl)ammonium methylsulfate 
• 1358418-50-4 N-cyanomethyl-N,N-dimethyl-N-(α-methoxycarbonylbenzyl)ammonium bromide 
• 37167-62-7 bromo-phenyl-acetic acid methyl ester 

Downstream Products

• 116206-45-2 Methyl 2-<3-oxo-4-(3-chlorophenoxy)-1E-butenyl>phenylacetate 
• 116206-43-0 2-(3-oxo-1E-octenyl)phenylacetic acid methyl ester 
• 6772-68-5 2-phenyl-1,4-dihydroisoquinolin-3(2H)-one 
• 24331-94-0 1,4-dihydro-3(2H)-isoquinolinone 
• 6772-73-2 1,4-dihydro-2-(phenylmethyl)-3(2H)-isoquinolinone 

Relevant articles and documents

Photochemistry of 1,3-bis(diazo)indan-2-one: Consecutive decomposition and suppression of a Wolff rearrangement

The photodecomposition processes of 1,3-bis(diazo)indan-2-one (19) have been investigated by the characterization of reaction products in fluid solutions and by the direct observation of reactive intermediates in matrices at cryogenic temperatures. Irradi

Sigmatropic rearrangement of ammonium ylideskey step in the synthesis of methyl 2-formylphenyl acetate

N-Cyanomethyl-N,N-dimethyl-N-(-methoxycarbonyl)benzylammonium salts 5 were synthesized and treated with different base/solvent systems, giving the products of sigmatropic rearrangements [2,3] 7 and [1,2] 8. In reactions carried out in liquid ammonia, [2,3] rearrangement definitively prevailed. Pure 7(or mixture of 7 and 8) were deprotected to afford methyl 2-formylphenyl acetate (9) in good yield.

Methyl α-arylacrylates substituted by a heterocyclic radical and their use

Methyl α-arylacrylates substituted by a heterocyclic radical and having the general formula STR1 where R is alkyl, alkenyl, haloalkyl, cycloalkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, halogen or aryl, the aromatic ring being unsubstituted or substituted, Het is a five-membered heteroaromatic ring which is unsubstituted or substituted and has from one to three heteroatoms, and A is ethenylene, ethylene, methyleneoxy or methylenethio, and fungicides and pesticides containing these compounds.