639808-08-5

Basic information

• Product Name: E/Z-12-[(2S,3R,4S,5R)-3-allyloxy-5-azidomethyl-4-tert-butyldiphenylsilanyloxytetrahydrofuran-2-yl]dodec-11-enoic acid
• Synonyms: E/Z-12-[(2S,3R,4S,5R)-3-allyloxy-5-azidomethyl-4-tert-butyldiphenylsilanyloxytetrahydrofuran-2-yl]dodec-11-enoic acid
• CAS NO: 639808-08-5
• Molecular Weight: 633.904
• Mol File: 639808-08-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: E/Z-12-[(2S,3R,4S,5R)-3-allyloxy-5-azidomethyl-4-tert-butyldiphenylsilanyloxytetrahydrofuran-2-yl]dodec-11-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: E/Z-12-[(2S,3R,4S,5R)-3-allyloxy-5-azidomethyl-4-tert-butyldiphenylsilanyloxytetrahydrofuran-2-yl]dodec-11-enoic acid(639808-08-5)
• EPA Substance Registry System: E/Z-12-[(2S,3R,4S,5R)-3-allyloxy-5-azidomethyl-4-tert-butyldiphenylsilanyloxytetrahydrofuran-2-yl]dodec-11-enoic acid(639808-08-5)

Safety Data

• Hazardous Substances Data: 639808-08-5(Hazardous Substances Data)

Upstream product

• 639808-06-3 3-O-allyl-2,5-anhydro-6-azido-4-O-tert-butyldiphenylsilanyl-6-deoxy-1-O-triphenylmethyl-D-glucitol 
• 639808-05-2 2,5-anhydro-6-azido-4-O-tert-butyldiphenylsilanyl-6-deoxy-1-O-triphenylmethyl-D-glucitol 
• 639808-07-4 3-O-allyl-2,5-anhydro-6-azido-4-O-tert-butyldiphenylsilanyl-6-deoxy-D-glucitol 
• 639808-04-1 2,5-anhydro-6-azido-4-O-tert-butyldiphenylsilanyl-6-deoxy-1,3-O-isopropylidene-D-glucitol 
• 639808-20-1 2,5-anhydro-6-azido-4-O-tert-butyldiphenylsilanyl-6-deoxy-D-glucitol 
• 813436-33-8 2,5-anhydro-6-azido-6-deoxy-1,3-O-isopropylidene-D-glucitol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 106248-72-0 2,5-Anhydro-1,3-O-isopropyliden-6-O-(p-tosyl)-D-glucitol 
• 7530-96-3 (11-carboxyundecyl)triphenylphosphonium bromide 

Relevant articles and documents

The Use of a Mannitol-Derived Fused Oxacycle as a Combinatorial Scaffold

An efficient and high-yielding solid-phase synthesis of a small library of compounds containing a cis-fused pyranofuran structural motive is descibed. With use of the cheap and readily available D-(+)-mannitol, a highly functionalized sugar template was synthesized and immobilized on a solid support via an olefinic linker. Modification of this two-point molecular scaffold and subsequent ring-closing metathesis/cleavage gave access to a series of functionalized conformationally constrained fused oxacycles.