64298-96-0

Basic information

• Product Name: Glutamic acid, 2-methyl-N-(phenylmethylene)-, dimethyl ester
• CAS NO: 64298-96-0
• Molecular Formula: C15H19NO4
• Molecular Weight: 277.32
• Mol File: 64298-96-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Glutamic acid, 2-methyl-N-(phenylmethylene)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Glutamic acid, 2-methyl-N-(phenylmethylene)-, dimethyl ester(64298-96-0)
• EPA Substance Registry System: Glutamic acid, 2-methyl-N-(phenylmethylene)-, dimethyl ester(64298-96-0)

Safety Data

• Hazardous Substances Data: 64298-96-0(Hazardous Substances Data)

Upstream product

• 40216-71-5 methyl 2-(benzylideneamino)propanoate 
• 292638-85-8 acrylic acid methyl ester 
• 120328-90-7 methyl (E)-N-benzylidenealaninate 
• 100-52-7 benzaldehyde 
• 53933-42-9 2-(benzylidene-amino)-propionic acid methyl ester 

Downstream Products

• 75517-02-1 dimethyl 2-methyl-t-5-phenyl-r-2,c-4-pyrrolidinedicarboxylate 
• 75517-02-1 dimethyl 2-methyl-c-5-phenyl-r-2,c-4-pyrrolidine-dicarboxylate 
• 56145-24-5 methyl 2-methyl-5-oxopyrrolidine-2-carboxylate 

Relevant articles and documents

Solventless lactam synthesis by intramolecular cyclizations of α-iminoester derivatives under microwave irradiation

We have previously reported a new synthesis of amides from esters and amines under microwave irradiation, offering much higher yields than those achieved with conventional heating [1]. We have now extended these studies to the ring closure of neat iminoes

Generation of an N-Sodioazomethine Ylide and Its Cycloadditions with α,β-Unsaturated Esters

Treatment of methyl 2-(benzylideneamino)propanoate with sodium hydride in THF generates an N-sodioazomethine ylide, which shows a very poor stereoselectivity in the cycloaddition with methyl acrylate.However, addition of such a base as triethylamine or t-

X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 15. AMINE GENERATED AZAALLYL ANIONS VERSUS METALLO-1,3-DIPOLES IN CYCLOADDITIONS OF α-AMINO ACID ESTERS. FACILE REGIO- AND STEREO-SPECIFIC FORMATION OF PYRROLIDINES.

Kinetic studies of the deprotonation of arylidine imines of alanine and phenylglycine esters by tertiary amines and pyridine and cycloaddition of the resultant 4?-azaallyl anions to N-phenylmaleimide show the expected dependance on the p-substituent in th