643024-91-3

Upstream product

• 98-88-4 benzoyl chloride 
• 643024-90-2 (R)-1-((3aR,4R,6R,6aR)-6-Methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-3-phenyl-prop-2-yn-1-ol 

Downstream Products

• 883860-01-3 Benzoic acid (R)-1-((2S,3S,4R,5R)-3,4-dihydroxy-5-methoxy-tetrahydro-furan-2-yl)-3-phenyl-prop-2-ynyl ester 
• 883860-02-4 Benzoic acid (R)-1-[(2R,3R,4R,5R)-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-tetrahydro-furan-2-yl]-3-phenyl-prop-2-ynyl ester 
• 883860-03-5 Acetic acid (E)-(R)-1-[(2R,3R,4R,5R)-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-tetrahydro-furan-2-yl]-3-phenyl-allyl ester 
• 883860-06-8 Acetic acid (2R,3R,3aR,5R,6R,7S,7aS)-3-acetoxy-2-methoxy-5-phenyl-6-phenylselanyl-hexahydro-furo[3,2-b]pyran-7-yl ester 
• 1053642-13-9 Acetic acid (2R,3R,3aS,5R,6R,7S,7aS)-3-hydroxy-2-methoxy-5-phenyl-6-phenylselanyl-hexahydro-furo[3,2-b]pyran-7-yl ester 
• 883860-07-9 Acetic acid (2R,3R,3aR,5S,7R,7aR)-7-acetoxy-2-methoxy-5-phenyl-hexahydro-furo[3,2-b]pyran-3-yl ester 
• 883860-04-6 Acetic acid (E)-(R)-1-((2S,3S,4R,5R)-3,4-dihydroxy-5-methoxy-tetrahydro-furan-2-yl)-3-phenyl-allyl ester 

Relevant academic research and scientific papers

Synthesis of the bicyclic core of the nucleoside antibiotic octosyl acid A

The bicyclic core of octosyl acid A has been prepared using a diastereoselective acetylide addition and 6-endo selenoetherification as key steps. A detailed study of the selenoetherification reaction and difficulties encountered in the conversion of a phe