64395-03-5

Usage

Parent compound

Benzenedicarboxylic acid

Derivative

Contains bromine and tert-butyl groups

Applications

a. Production of polymers (polyesters and polyamides)
b. Functionalized polymers with specific properties
c. Improved thermal stability
d. Flame resistance
e. Pharmaceutical industry
f. Agricultural industry

Upstream product

• 100620-25-5 (2-bromo-5-tert-butyl-3-methyl-benzyl)-methyl ether 
• 5345-05-1 4-t-butyl-2,6-dimethylbromobenzene 
• 98-19-1 5-tert-Butyl-m-xylene 
• 104851-47-0 2-bromo-1-bromomethyl-5-tert-butyl-3-methylbenzene 

Downstream Products

• 75893-84-4 bis<2,6-dicarboxy-4-(1,1-dimethylethyl)phenyl> sulfide 
• 64407-86-9 2-mercapto-5-tert-butylisophthalic acid 
• 75893-95-7 2-phenylthio-5-tert-butylisophthalic acid 
• 259197-87-0 2-bromo-5-tert-butyl-isophthalic acid dimethyl ester 
• 1315258-25-3 2-bromo-5-tert-butyl-1,3-bis[N-(2-chloroethyl)carbamoyl]benzene 
• 1315258-28-6 [t-BuPheBox-H₂]Br 
• 1315258-29-7 [t-BuPheBox-Me₂]Br 
• 1315258-26-4 2-bromo-5-tert-butyl-N-(1-chloro-2-methylpropan-2-yl)-3-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)benzamide 
• 1361152-38-6 C₁₈H₂₃BrN₂O₆ 
• 1361152-41-1 C₂₂H₃₂N₂O₆Se 
• 1427004-31-6 C₃₈H₄₅BrN₄ 
• 1427038-32-1 C₃₈H₄₅BrN₄Ni 
• 101697-26-1 2‐[2‐bromo‐5‐tert‐butyl‐3‐(1,1,1,3,3,3‐hexafluoro‐2‐hydroxypropan‐2‐yl)phenyl]‐1,1,1,3,3,3‐hexafluoropropan‐2‐ol 
• 342400-64-0 5-tert-Butyl-2-methylsulfanyl-isophthalic acid 

Relevant academic research and scientific papers

Electrochemical Generation of Hypervalent Bromine(III) Compounds

In sharp contrast to hypervalent iodine(III) compounds, the isoelectronic bromine(III) counterparts have been little studied to date. This knowledge gap is mainly attributed to the difficult-to-control reactivity of λ3-bromanes as well as to their challenging preparation from the highly toxic and corrosive BrF3 precursor. In this context, we present a straightforward and scalable approach to chelation-stabilized λ3-bromanes by anodic oxidation of parent aryl bromides possessing two coordinating hexafluoro-2-hydroxypropanyl substituents. A series of para-substituted λ3-bromanes with remarkably high redox potentials spanning a range from 1.86 V to 2.60 V vs. Ag/AgNO3 was synthesized by the electrochemical method. We demonstrate that the intrinsic reactivity of the bench-stable bromine(III) species can be unlocked by addition of a Lewis or a Br?nsted acid. The synthetic utility of the λ3-bromane activation is exemplified by oxidative C?C, C?N, and C?O bond forming reactions.

The substituent effect of bridged triarylamine helicenes on light-emitting and charge transfer properties

Methoxy-(7a), bromo-(7b), CF3-(7c) and hydroxyl-(7d) substituted bridged triarylamine helicenes were synthesized under mild conditions in 6598% yield. Their luminescence red-shifted with π-donating substituents and blue-shifted with the electro

Heterocyclic compounds and organic light-emitting diode including the same

The present invention relates to a heterocyclic compound represented by [Chemical Formula 1] below and an organic light-emitting diode including the same. The organic light-emitting diode according to the present invention is excellent in view of luminous characteristics such as driving voltage, lifespan, and efficiency. [Chemical Formula 1].

Bridged triarylamines: A new class of heterohelicenes

A series of bridged triarylamines, which constitute a new class of heterohelicenes, have been synthesized using a simple three-step procedure. These compounds are shown to be highly luminescent chromophores and are capable of being oxidized. The solid-sta

Formation and rearrangement of dithioxo- and diselenoxophosphoranes carrying bulky 4-t-butyl-2,6-bis(methoxyalkyl)phenyl groups

[4-t-Butyl-2,6-bis(1-methoxy-1-methylethyl)phenyl]phosphine, [4-t-butyl- 2,6-bis(2-methoxy-1,1-dimethylethyl)phenyl]phosphine, and [4-t-butyl-2,6- bis(3-methoxy-1,1-dimethylpropyl)phenyl]phosphine were prepared and allowed to react with sulfur or selenium, to give heterocyclic compounds containing phosphorus-oxygen bond, via rearrangement of the methyl moiety of the methoxy group.

Solution and solid state studies of some new silicon and germanium compounds stabilized by tridentate ligands

The preparation and studies of novel heterocyclic compounds, containing silicon or germanium, is described. All of them incorporate the 2,6-bis(dialkylaminomethyl)-4-(1,1-dimethylethyl)phenyl tridentate ligand (Structures 1-2, Scheme 1) as a main substruc

Synthesis and NMR Characterization of Bis-Strapped Six-coordinate Fe(II) Cytochrome-C Model

The new hexadentate bis-strapped porphyrin 6 has been synthesized with two different ansa, bringing in an intramolecular way, a nitrogen base and a thioether sixth ligand both necessary to mimic the natural cytochrome-C protein. 1H NMR spectroscopy indicates clearly the six coordination of the iron atom.Key Words: cytochrome-C/ porphyrin/ modelisation/ six-coordinate Fe(II)