64450-18-6

Upstream product

• 108-24-7 acetic anhydride 
• 103-01-5 N-Phenylglycine 
• 102860-03-7 N-(2-methylprop-2-ene-1-yl)-N-phenylacetamide 
• 22094-23-1 2-acetoxypropanal 
• 62-53-3 aniline 
• 108-05-4 vinyl acetate 
• 201230-82-2 carbon monoxide 
• 14465-74-8 N-phenyl-N-prop-2-ynylamine 
• 55487-54-2 N-allyl-N-phenylacetamide 

Downstream Products

• 101593-30-0 N-[2-(4-nitro-phenylhydrazono)-propyl]-acetanilide 
• 121974-50-3 (4-nitro-anilino)-acetone 

Relevant academic research and scientific papers

Synthesis of α-Amidoketones from Vinyl Esters via a Catalytic/Thermal Cascade Reaction

A straightforward, modular, and atom-efficient method is reported for the synthesis of α-amidoketones from vinyl esters via a cascade reaction including hydroformylation, condensation with a primary amine, and a rearrangement step giving water as the only byproduct. The reaction sequence can be performed in one pot or as a three-step procedure. The synthetic applicability is demonstrated by the preparation of different α-amidoketones in moderate to good yields.

Use of the composite material RuO2/BaTi4O9 as an environmentally benign solid catalyst for the oxidative cleavage of olefins

Catalytic use of a composite material, RuO2/BaTi 4O9, in combination with NaIO4 in EtOAc-H 2O has been shown to efficiently cleave alkenes, affording ketones, aldehydes and/or carboxylic acids in high yields. Georg Thieme Verlag Stuttgart.