64482-96-8Relevant academic research and scientific papers
New access to organoacyloxytrialkylsilanes
Mancardi, David,Sindt, Michele,Paul, Jean-Michel,Mieloszynski, Jean-Luc
, p. 3879 - 3884 (2008/02/10)
In this article, we present the synthesis of acetoxytributylsilane, obtained from methoxytributylsilane and acetic anhydride, under different conditions (catalyst, temperature, reaction time). Access to other acyloxytributylsilanes from different anhydrides is also presented. Copyright Taylor & Francis Group, LLC.
Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters
Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies
, p. 2717 - 2727 (2008/02/12)
Tris(triphenylphosphine)cuprous chloride [Cu(PPh3)3Cl] has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol% Cu(PPh3)3Cl, dehydrosilylation reactions in acetonitrile afforded the corresponding silyl esters at 80°C in good yields. It was noted that triphenylphosphine itself also functions as an adequate catalyst for the reaction. Copyright Taylor & Francis Group, LLC.
Preparation of silyl esters by ZnCl2-catalyzed dehydrogenative cross-coupling of carboxylic acids and silanes
Liu, Guo-Bin
, p. 1431 - 1433 (2007/10/03)
An efficient route to silyl esters by dehydrogenative cross-coupling of silanes and carboxylic acids was investigated. Treatment of silanes and carboxylic acids in the presence of 15mol% of ZnCl2 in DMF at 120 °C afforded the corresponding silyl esters in good yields under relatively mild conditions. Georg Thieme Verlag Stuttgart.
