15811-64-0Relevant articles and documents
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Lacout-Loustalet,M.B. et al.
, p. 337 - 368 (1971)
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Silyl group deprotection by Pd/C/H2. A facile and selective method
Kim, Seongjin,Jacobo, Sheila Marie,Chang, Chih-Tsung,Bellone, Sophie,Powell, William S.,Rokach, Joshua
, p. 1973 - 1976 (2007/10/03)
An easy, high yield, RT, short-reaction-time Pd/C hydrogenation of silyl groups is described. This includes TES, TPS, TBS, TBDMS, TIPS, and TBDPS. The relative selectivity of the process has been investigated and we can show, for example, that TES, TPS, TBS, and TBDMS removal can be performed in the presence of TIPS and TBDPS.