645-68-1

Usage

InChI:InChI=1/C14H22O/c1-11(2)13(4)10-9-12(3)7-6-8-14(5)15/h6-8H,9-10H2,1-5H3/b8-6+,12-7+

Upstream product

• 3899-32-9 (E)-3,6,7-trimethylocta-2,6-dien-1-ol 
• 555-31-7 aluminum isopropoxide 
• 67-64-1 acetone 
• 556-91-2 aluminum tri-tert-butoxide 
• 64708-55-0 3-Hydroxy-4-isopropenyl-3,6,7-trimethyl-6-octen-1-yne 
• 78424-77-8 4-Benzenesulfonyl-9,10-dimethyl-6-methylene-undec-9-en-2-one 
• 72445-16-0 2-(Chloromethyl)-4-(phenylthio)-1-butene 
• 78424-78-9 (2,3-dimethyl-2-butenyl)magnesium chloride 
• 78424-80-3 (6,7-Dimethyl-3-methylene-oct-6-enylsulfanyl)-benzene 
• 64708-53-8 5,6-Dimethyl-3-isopropenyl-2-oxo-5-heptene 
• 52567-96-1 3,6,7-trimethyl-oct-6-en-1-yn-3-ol 
• 687-68-3 5,6-dimethyl-5-hepten-2-one 
• 58307-67-8 3,6,7-trimethyl-6-octen-1-en-3-ol 
• 37866-06-1 1-chloro-2,3-dimethyl-but-2-ene 

Downstream Products

• 72074-84-1 beta-irone 
• 72074-86-3 (+-)-4t-(2,5t,6,6-Tetramethyl-cyclohex-2-en-r-yl)-but-3-en-2-on 
• 79-69-6 (+/-)-α-Iron 
• 72074-85-2 (+-)-4t-(2,5c,6,6-tetramethyl-cyclohex-2-en-r-yl)-but-3-en-2-one 
• 79-70-9 β-irone 
• 6138-84-7 (+/-)-4-(2,2,3t,6c-tetramethyl-cyclohex-r-yl)-butan-2-one 
• 16769-63-4 (+/-)-4-(2,2,3t,6c-tetramethyl-cyclohex-r-yl)-butan-2-one semicarbazone 
• 27687-81-6 (+/-)-4t-(2,5,6,6-tetramethyl-cyclohex-1-enyl)-but-3-en-2-one-(2,4-dinitro-phenylhydrazone); (+/-)-trans-β-iron-(2,4-dinitro-phenylhydrazone) 
• 162282-94-2 1-(1,3,4-trimethyl-3-cyclohexenyl)-1-penten-4-one 
• 79-68-5 gamma-irone 
• 81456-93-1 (1'RS,5'RS)-4-(2',5',6',6'-tetramethylcyclohex-2'-enyl)butan-2-one 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF IONONES AND IRONES FROM 2-HYDROXYMETHYL-4-PHENYLTHIO-1-BUTENE

A sequence of allylation, the Wacker reaction, and desulfonylation of homoallyl sulfones provided a new synthetic method for the α,β,γ,δ-unsaturated ketone system often encountered in natural products.This procedure was successfully applied to ionone and irone synthesis.