64526-69-8Relevant articles and documents
Direct glycosylation of unprotected and unactivated carbohydrates under mild conditions
Pfaffe, Matthias,Mahrwald, Rainer
, p. 792 - 795 (2012)
Ligand exchange acetalization of acetals in the presence of catalytic amounts of mandelic acid and titanium tert-butoxide is reported. This transformation is successfully extended to glycosylation of unprotected and unactivated pentoses. Even unreactive pentoses such as d-arabinose or d-lyxose can be transformed by this new methodology into corresponding isopropyl glycosides.