645386-38-5Relevant academic research and scientific papers
Highly convergent, stereospecific synthesis of 11-cis-retinoids by metal-catalyzed cross-coupling reactions of (Z)-1-alkenylmetals
Lopez, Susana,Montenegro, Javier,Saa, Carlos
, p. 9572 - 9581 (2008/04/05)
(Chemical Equation Presented) A stereospecific synthesis of 11-cis-retinoids has as its key step the hitherto unexplored palladium-catalyzed cross-coupling of trans-tnenyl electrophiles and (1Z,3E)-penta-1,3-dienyl boronates (a Suzuki-Miyaura reaction) or
Intramolecular Formal oxa-[3 + 3] Cycloaddition Approach to the ABD System of Phomactin A
Cole, Kevin P.,Hsung, Richard P.
, p. 4843 - 4846 (2007/10/03)
(Equation Presented) The ABD-ring of phomactin A was synthesized using an intramolecular formal oxa-[3 + 3] cycloaddion of an α,β-unsaturated iminium salt tethered to a 1,3-diketone. This represents the first time that the 12-membered ring has been formed
