645388-77-8

Upstream product

• 67175-79-5 2-(4-methoxycyclohexa-1,4-dienyl)ethylamine 
• 15930-53-7 6-bromo-3,4-methylenedioxybenzaldehyde 

Downstream Products

• 10313-37-8 4-{2-[(6-bromo-benzo[1,3]dioxol-5-ylmethyl)-amino]-ethyl}-cyclohex-2-enone 
• 63814-03-9 1,2,3,3a,4,5,12b,12c-octahydro-7H-1,3-benzodioxolo[5,6-c]pyrrolo[3,2,1-ij]quinoline 
• 34315-37-2 4-{2-[(6-bromo-benzo[1,3]dioxol-5-ylmethyl)-amino]-ethyl}-phenol 
• 1609159-33-2 C₁₆H₂₀BrNO₃ 
• 1609159-34-3 C₂₂H₃₄BrNO₃Si 

Relevant academic research and scientific papers

Synthesis of the putative structure of (±)-amarbellisine

The title compound was synthesized mainly by palladium catalytic coupling, cyclopropyl ring-opening rearrangement, epoxidation, Swern oxidation, demethanol reactions, and selective reduction. This synthesis was achieved in 16 steps with 9.7% overall yield

Total synthesis of lycorine-type alkaloids by cyclopropyl ring-opening rearrangement

A practical method for the synthesis of lycorine-type alkaloids with cis-B/C ring structure has been developed. Based on the reactions of aminocyclization, palladium-mediated arylation and especially cyclopropyl ring-opening rearrangement, the synthesis o

An Efficient Palladium Mediated Synthesis of (±)-γ-Lycorane

An intramolecular approach incorporating a Michael addition followed by a palladium-mediated arylation of ketone towards the synthesis of Amaryllidaceae alkaloid (±)-γ-lycorane was reported.