6455-30-7Relevant academic research and scientific papers
Dinitrofuroxan cycloreversion as a novel general approach for the synthesis of nitroazoles
Fershtat,Khakimov,Makhova
, p. 415 - 422 (2015)
A novel general approach towards various nitroazoles via tandem process involving dinitrofuroxan cycloreversion followed by [3+2] cycloaddition of generated in situ nitroformonitrile oxide is developed. The reaction is promoted by addition of catalytic am
Ionic liquid-promoted [3+2]-cycloaddition reactions of nitroformonitrile oxide generated by the cycloreversion of dinitrofuroxan
Fershtat, Leonid L.,Ovchinnikov, Igor V.,Makhova, Nina N.
supporting information, p. 2398 - 2400 (2014/05/06)
A new approach to the synthesis of 3-nitroisoxazoles and 3-nitroisoxazolines based on the [3+2]-cycloaddition of nitroformonitrile oxide (NFNO), generated by the cycloreversion of dinitrofuroxan (DNFO), to acetylene and ethylene derivatives, under ionic liquid catalysis is developed. The approach is of a general nature and applicable to cycloaddition reactions with other dipolarophiles.
3-NITROISOXAZOLES AND THEIR USE IN THE PROTECTION OF MATERIALS
-
, (2012/09/11)
The 3-nitroisoxazoles of the formula (I) in which R1 and R2 are each as defined in the description, some of which are known, are highly suitable for use as biocides for protecting industrial materials.
Reaction of propargyl bromides with silver and sodium nitrites. A new method for the synthesis of nitroisoxazoles
Mechkov, Ts. D.,Sulimov, I. G.,Usik, N. V.,Mladenov, I.,Perekalin, V. V.
, p. 1148 - 1150 (2007/10/02)
The reaction of primary and secondary propargyl bromides with silver and sodium nitrites was investigated for the first time.In contrast to alkyl and allyl halides, the reaction does not stop at the stage of the formation of the normal mononitro compounds for the Meyer - Kornblum reaction and results in the synthesis of derivatives of 3- or 4-nitroisoxazoles.
