64583-20-6Relevant academic research and scientific papers
Cross-coupling reactivity of 1,1-dichloroalkenes under palladium catalysis: Domino synthesis of diarylalkynes
Maddali, L. N. Rao,Meka, Suresh
supporting information, p. 4412 - 4418 (2018/03/21)
An efficient synthesis of diarylalkynes was achieved from the domino cross-coupling reaction of 1,1-dichloroalkenes with triarylbismuth reagents under palladium-catalyzed conditions. Under the established palladium protocol, 1,1-dichloroalkenes demonstrated hitherto unknown remarkable cross-coupling reactivity with organometallic triarylbismuth reagents to furnish functionalized diarylalkynes.
Cu-catalyzed decarboxylative coupling of propiolic acids with boronic acids
Shi, Leilei,Jia, Wei,Li, Xun,Jiao, Ning
supporting information, p. 1951 - 1955 (2013/04/10)
A mild procedure of Cu-catalyzed decarboxylative cross-coupling of aryl- and alkynyl-boronic acids for construction of unsymmetrical substituted alkynes has been developed. The usage of inexpensive copper chloride as catalyst, and employing stable alkynl carboxylic acids and boronic acids as the substrates under oxidative conditions for sp-sp2 coupling, make this method very easy to operate.
METABOTROPIC GLUTAMATE RECEPTORS 5 MODULATORS AND METHODS OF USE THEREOF
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Page/Page column 97, (2012/12/13)
Compounds that modulate GluR5 activity and methods of using the same are disclosed.
Synthesis and non-linear properties of disubstituted diphenylacetylene and related compounds
Kondo, Koichi,Fujitani, Takumi,Ohnishi, Noriaki
, p. 429 - 433 (2007/10/03)
A variety of disubstituted diphenylacetylenes and related compounds have been synthesized by a modified Horner-Emmons reaction, and their second harmonic generation (SHG) has been evaluated by the Kurtz powder method. The diphenylacetylenes with weak electron-donating and -withdrawing groups are found to be efficient for SHG, as well as having the lowest cut-off wavelength.
