437-29-6

Basic information

• Product Name: tris(4-fluorophenyl)bismuthane
• Synonyms: tris(4-fluorophenyl)bismuthane
• CAS NO: 437-29-6
• Molecular Weight: 494.269
• Mol File: 437-29-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: tris(4-fluorophenyl)bismuthane(CAS DataBase Reference)
• NIST Chemistry Reference: tris(4-fluorophenyl)bismuthane(437-29-6)
• EPA Substance Registry System: tris(4-fluorophenyl)bismuthane(437-29-6)

Safety Data

• Hazardous Substances Data: 437-29-6(Hazardous Substances Data)

Upstream product

• 7439-95-4 magnesium 
• 25776-12-9 sodium tetrakis(4-fluorophenyl)borate 
• 352-13-6 4-flourophenylmagnesium bromide 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 19034-57-2 Bi(2-HO-C₆H₄CO₂)3 
• 7787-60-2 bismuth(III) chloride 
• 7440-69-9 bismuth 
• 352-34-1 4-fluoro-1-iodobenzene 

Downstream Products

• 479586-34-0 (R)-3-(4-fluorophenyl)cyclohexanone 
• 121900-00-3 bis(acetato)tris(4-fluoro-phenyl)bismuth 
• 345-83-5 4-fluorobenzophenone 
• 398-23-2 4,4'-difluorobiphenyl 
• 347-84-2 1-(4-fluorophenyl)-2-phenylethanone 
• 1196493-34-1 C₁₄H₉Cl₂FO 
• 398-24-3 4-fluoro-4'-nitro-1,1'-biphenyl 
• 10540-32-6 1‐(4‐fluorophenyl)‐3‐nitrobenzene 
• 1239896-81-1 4-(4-fluorophenyl)-5,7-dimethyl-2H-chromen-2-one 
• 120346-46-5 4-(4-fluorophenyl)-2H-benzopyran-2-on 
• 10540-31-5 4-cyano-4'-fluorobiphenyl 
• 388-65-8 4-(4-fluorophenyl)-1,2-dihydronaphthalene 
• 134294-43-2 2-methylene 3-(4-fluorophenyl) propanoate d'ethyle 
• 66548-52-5 3-chloro-6-(4-fluorophenyl)pyridazine 

Relevant articles and documents

Synthesis of highly functionalized triarylbismuthines by functional group manipulation and use in palladium- and copper-catalyzed arylation reactions

Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpensive and nontoxic bismuth salts. Triarylbismuthines are particularly interesting due to their air and moisture stability and high functional group tolerance. We report herein a detailed study on the preparation of highly functionalized triarylbismuth reagents by triple functional group manipulation and their use in palladium- and copper-catalyzed C-, N-, and O-arylation reactions.

Palladium-catalyzed cross-coupling reaction of functionalized aryl- and heteroarylbismuthanes with 2-halo(or 2-Triflyl)azines and -diazines

The palladium-catalyzed cross-coupling of highly functionalized organobismuthanes with 2-halo(or 2-triflyl)pyridines, -pyrimidines, -pyrazines, and -pyridazines is reported. The reaction tolerates numerous functional groups, including aldehydes. The synthesis of a shelf-stable (formylphenyl)bismuth reagent and its use in a cross-coupling reaction is also described. The palladium-catalyzed cross-coupling of highly functionalized organobismuthanes with 2-halo(or 2-triflyl)pyridines, -pyrimidines, -pyrazines, and -pyridazines is reported. The reaction tolerates numerous functional groups, including aldehydes. The synthesis of a shelf-stable (formylphenyl)bismuth reagent and its use in cross-coupling reactions is also described. Copyright

4-ARYLMORPHOLIN-3-ONE DERIVATIVES, THEIR PREPARATION AND THERAPEUTIC USE THEREOF

The invention relates to compounds corresponding to formula (I): in which: Ar represents a mono- or disubstituted phenyl; R1 represents an unsubstituted or substituted phenyl; R2 represents: a pyridyl; an unsubstituted or substituted phenyl; a benzyl that is unsubstituted or substituted on the phenyl; R2 may moreover represent: a heterocyclic radical; R3 represents various values. The invention also comprises methods for the compounds preparation, formulations comprising them and therapeutic applications thereof.