64584-01-6

Basic information

• Product Name: 1-Butyl-2-phenylcyclopropan
• Synonyms: 1-Butyl-2-phenylcyclopropan
• CAS NO: 64584-01-6
• Molecular Weight: 174.286
• Mol File: 64584-01-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Butyl-2-phenylcyclopropan(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butyl-2-phenylcyclopropan(64584-01-6)
• EPA Substance Registry System: 1-Butyl-2-phenylcyclopropan(64584-01-6)

Safety Data

• Hazardous Substances Data: 64584-01-6(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 109-72-8 n-butyllithium 
• 3234-51-3 1,1-dibromo-2-phenylcyclopropane 
• 592-41-6 1-hexene 
• 908094-04-2 phenyldiazomethane 

Relevant articles and documents

Reactions of gem-dibromo compounds with trialkylmagnesate reagents to yield alkylated organomagnesium compounds

The reaction of gem-dibromocyclopropanes 5 with nBu3MgLi affords butylated cyclopropylmagnesium species that can be trapped with various electrophiles. The reaction of dibromomethylsilanes 12 requires the addition of a catalytic amount of CuCN · 2 LiCl for smooth migration of the alkyl groups. The resultant α-silylpentylmagnesium compounds 16 react with electrophiles, such as acyl chlorides or α, β-unsaturated ketones to afford α- or γ-silyl ketones, respectively. Treatment of dibromodisilylmethanes with Me3MgLi yields 1-bromo- 1,1-disilylethanes 25 that can be converted into 1,1-disilylethenes 29 by dehydrobromination.