64638-70-6Relevant academic research and scientific papers
Chiral Building Units from Carbohydrates, XI. - 2-Lithio-1,3-dithiane-induced Reactions of 5,6-Dideoxy-5-iodohexofuranoses Leading to Open-chained Heptose Trimethylene Dithioacetals
Redlich, Hartmut,Lenfers, Jan Bernd,Bruns, Wilfried
, p. 1570 - 1586 (2007/10/02)
The reaction of 5,6-dideoxy-5-iodohexofuranoses 5b, 7c, 8, 8a, and 20 with a large excess of 2-lithio-1,3-dithiane (1) yields the open-chained heptose trimethylene dithioacetals 21, 23, 24, 25, and 26.L-Configurated 5-iodides give Z-olefines, D-configurat
Chiral Synthesis of Polyketide-derived Natural Products. Part 4. Synthesis of a Left-hand Segment with Six Consecutive Chiral Centres of Dihydroerythronolide A for the Total Synthesis of Erythromycin A from D-Glucose
Oikawa, Yuji,Nishi, Takao,Yonemitsu, Osamu
, p. 7 - 18 (2007/10/02)
For the purpose of the total synthesis of erythromycin A (1) from D-glucose (2) with the aid of stereochemical control in acyclic systems and p-methoxyphenylmethyl (MPM) protection, (2R,3S,4S,5R,6R,7R)-1-hydroxy-5,6-isopropylidenedioxy-3,7-bis(4-methoxybe
