55533-86-3

Upstream product

• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 100-39-0 benzyl bromide 
• 35784-67-9 1,2:5,6-di-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 55533-85-2 3-O-benzyl-1,2:5,6-di-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-ribo-3-hexulofuranose 
• 350255-13-9 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 35784-67-9 1,2;5,6-di-O-isopropylidene-3-C-methyl-α-D-allofuranose 

Downstream Products

• 81841-44-3 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-α-D-ribopentodialdo-1,4-furanose 
• 110808-85-0 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-6-O-methylbenzoyl-α-D-allofuranose 
• 98003-97-5 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-5,6-ditosyloxy-α-D-allofuranose 
• 99050-12-1 3-O-Benzyl-1,2-O-isopropyliden-3-C-methyl-6-O-(p-tolylsulfonyl)-α-D-allo-hexofuranose 
• 132000-21-6 (5S)-5-O-Acetyl-3-O-benzyl-3-C-methyl-1,2-O-isopropylidene-5-(1,4-diacetoxy-9',10'-dihydro-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose hemihydrate 
• 132000-27-2 (4S)-2-C-Methyl-2-O-benzyl-3-O-formyl-4-(9',10'-dihydro-1',4'-dihydroxy-9,10-dioxo-2-anthryl)-α,β-D-erythro-tetrafuranose 
• 132000-32-9 (8R,9S,10R)-8-O-Benzyl-8-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-hexahydroxynaphthacene-5,12-dione 
• 132000-37-4 (8R,9S,10S)-8-O-Benzyl-8-C-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-hexahydroxynaphthacene-5,12-dione 
• 132000-23-8 (5S)-3-O-Benzyl-3-C-methyl-5-(9',10'-dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α,β-D-ribopyranose 
• 132000-30-7 (4S)-2-O-Benzyl-2-C-methyl-3-O-formyl-4-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2-anthryl)-α,β-D-erythro-tetrafuranose 
• 132000-30-7 (4R)-2-O-Benzyl-2-C-methyl-3-O-formyl-4-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2'-anthryl)-α(β)-D-erythro-tetrafuranose hemihydrate 
• 132000-33-0 (7R/S)-8R,9S,10R-8-O-Benzyl-8-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-heptahydroxynaphthacene-5,12-dione 
• 132000-33-0 (7R/S,8R,9S,10S)-8-O-Benzyl-3-C-methyl-7,8,9,10-tetrahydro-4,6,7,8,9,10,11-heptahydroxynaphthacene-5,12-dione 
• 132000-34-1 (5R)-3-O-Benzyl-3-C-methyl-5-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2'-anthryl)-α-β-D-ribopyranose 

Relevant academic research and scientific papers

Practical synthesis of a potent hepatitis C virus RNA replication inhibitor

A practical, efficient synthesis of 1, a hepatitis C virus RNA replication inhibitor, is described. Starting with the inexpensive diacetone glucose, the 12-step synthesis features a novel stereoselective rearrangement to prepare the key crystalline furanose diol intermediate. This is followed by a highly selective glycosidation to couple the C-2 branched furanose epoxide with deazapurine.

Anthracyclinones. Part 5. Synthesis of Some Anthracyclinones and 4-Hydroxyanthracyclinones containing a Tertiary Methyl Carbinol Function in Ring A from D-Glucose Precursors

Reaction of 3-C-Methyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (8a) with leucoquinizarin (2,3,4a,9a-tetrahydroanthracene-1,4,9,10-tetraone) (1a) in alkaline solution followed by aerial oxidation gave mainly (5S)-3-C-methyl 1,2-O-isopropylid