55533-86-3

Upstream product

• 350255-13-9 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 35784-67-9 1,2:5,6-di-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 55533-85-2 3-O-benzyl-1,2:5,6-di-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-ribo-3-hexulofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 35784-67-9 1,2;5,6-di-O-isopropylidene-3-C-methyl-α-D-allofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 

Downstream Products

• 81841-44-3 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-α-D-ribopentodialdo-1,4-furanose 
• 175408-82-9 2,2-Dimethyl-propionic acid (R)-2-((3aR,5R,6R,6aR)-6-benzyloxy-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-hydroxy-ethyl ester 
• 175408-78-3 1-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-(tert-butyl-dimethyl-silanyloxy)-ethanone 
• 175408-79-4 5-((3aR,5R,6R,6aR)-6-Benzyloxy-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-6-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2-methyl-hexan-3-one 
• 132000-22-7 (5R)-3-O-Benzyl-1,2-O-isopropylidene-3-C-methyl-5-(9',10'-dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose 
• 132000-20-5 (5S)-3-O-Benzyl-1,2-O-isopropylidene-3-C-methyl-5-(9',10'-dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose 
• 143033-02-7 (8R,9S)-9-O-benzyl-7,8,9,10-tetrahydro-6,8,9,10,11-pentahydroxy-9-methyl-5,12-naphthacenequinone 
• 143032-98-8 3-O-benzyl-3-C-methyl-5-deoxy-5-(quinizarin-2-yl)-α-D-ribofuranose 
• 143032-97-7 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-5-deoxy-5-(quinizarin-2-yl)-α-D-ribofuranose 
• 143033-01-6 (8R,9R,10R)-9-O-benzyl-7,8,9,10-tetrahydro-6,8,9,10,11-pentahydroxy-9-methyl-5,12-naphthacenequinone 
• 143033-00-5 (8R,9R,10S)-9-O-benzyl-7,8,9,10-tetrahydro-6,8,9,10,11-pentahydroxy-9-methyl-5,12-naphthacenequinone 
• 132000-21-6 (5S)-5-O-Acetyl-3-O-benzyl-3-C-methyl-1,2-O-isopropylidene-5-(1,4-diacetoxy-9',10'-dihydro-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose hemihydrate 
• 132000-27-2 (4S)-2-C-Methyl-2-O-benzyl-3-O-formyl-4-(9',10'-dihydro-1',4'-dihydroxy-9,10-dioxo-2-anthryl)-α,β-D-erythro-tetrafuranose 
• 132000-32-9 (8R,9S,10R)-8-O-Benzyl-8-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-hexahydroxynaphthacene-5,12-dione 

Relevant academic research and scientific papers

Practical synthesis of a potent hepatitis C virus RNA replication inhibitor

A practical, efficient synthesis of 1, a hepatitis C virus RNA replication inhibitor, is described. Starting with the inexpensive diacetone glucose, the 12-step synthesis features a novel stereoselective rearrangement to prepare the key crystalline furanose diol intermediate. This is followed by a highly selective glycosidation to couple the C-2 branched furanose epoxide with deazapurine.

Anthracyclinones. Part 5. Synthesis of Some Anthracyclinones and 4-Hydroxyanthracyclinones containing a Tertiary Methyl Carbinol Function in Ring A from D-Glucose Precursors

Reaction of 3-C-Methyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (8a) with leucoquinizarin (2,3,4a,9a-tetrahydroanthracene-1,4,9,10-tetraone) (1a) in alkaline solution followed by aerial oxidation gave mainly (5S)-3-C-methyl 1,2-O-isopropylid