64771-37-5Relevant academic research and scientific papers
Chemoselective formal β-functionalization of substituted aliphatic amides enabled by a facile stereoselective oxidation event
Bauer, Adriano,Maulide, Nuno
, p. 9836 - 9840 (2019/11/11)
Aliphatic C-H functionalization is a topic of current intense interest in organic synthesis. Herein, we report that a facile and stereoselective dehydrogenation event enables the functionalization of aliphatic amides at different positions in a one-pot fa
Pd(II)-catalyzed synthesis of indoles from α-aryloxime O-pentafluorobenzoates via intramolecular aromatic C-H amination
Chiba, Shunsuke,Zhang, Line,Sanjaya, Stephen,Ang, Gim Yean
experimental part, p. 5692 - 5700 (2010/10/02)
α-Aryl-a-aminocarbonyloxime O-pentafluorobenzoates are found to be promising precursors for synthesis of 2 3-disubstituted indole derivatives catalyzed by PdCl2(MeCN)2 in the presence of MgO as a base. The reaction is supposed to pro
The Vilsmeier-Haack Reaction of Isoxazolin-5-ones. Synthesis and Reactivity of 2-(Dialkylamino)-1,3-oxazin-6-ones
Beccalli, Egle M.,Marchesini, Alessandro
, p. 3426 - 3434 (2007/10/02)
The Vilsmeier-Haack reaction on isoxazolin-5-ones gives 2-(dialkylamino)-1,3-oxazin-6-ones, and a reaction path is proposed depending on substitution pattern of the isoxazolin-5-ones studied.A thermal equilibrium between the oxazinones, imino ketenes, and vinyl isocyanates is hypothesized to explain most of the chemical reactivity of the 2-(dialkylamino)-1,3-oxazin-6-ones.
