647834-99-9Relevant academic research and scientific papers
Highly Diastereoselective Conjugate Addition to Alkylidene Bis(Sulfoxides): Asymmetric Synthesis of (+)-erythro-Roccellic Acid
Brebion, Franck,Delouvrie, Benedicte,Najera, Francisco,Fensterbank, Louis,Malacria, Max,Vaissermann, Jacqueline
, p. 5342 - 5345 (2003)
Facial stereocontrol is possible in Michael additions of nucleophiles (Nu) to alkylidene bis(sulfoxides), which proceed via nonchelated (A) or chelated (B) intermediates depending on the addition of an appropriate Lewis acid (LA). This intriguing reactivi
