64857-61-0

Upstream product

• 74-96-4 ethyl bromide 
• 60951-19-1 (±)-N-ethyl-1,2-diphenylethylamine 
• 5097-99-4 α-diethylaminophenylacetonitrile 
• 25445-05-0 diethyl-(α-butoxy-benzyl)-amine 
• 1589-82-8 phenylmagnesium bromide 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 109-89-7 diethylamine 
• 100-52-7 benzaldehyde 
• 6921-34-2 benzylmagnesium chloride 
• 501-65-5 diphenyl acetylene 
• 87871-27-0 C₁₈H₂₁N 

Relevant academic research and scientific papers

Achieving Aliphatic Amine Addition to Arylalkynes via the Lewis Acid Assisted Triazole-Gold (TA-Au) Catalyst System

Transition metal catalyzed intermolecular hydroamination of the arylalkynes with aliphatic amine is generally problematic due to the good coordination between amine and metal cation. With the combination of 1,2,3-triazole coordinated gold(I) catalyst (TA-Au) and Zn(OTf)2 cocatalyst, this challenging transformation was achieved with good to excellent yields and regioselectivity. Compared to previously reported methods, this approach offered an alternative catalyst system to achieve this fundamental chemical transformation with high efficiency and practical conditions.

A New Method for the Synthesis of α-Substituted Phenethylamines via Titanium Amide Complexes

Substituted phenethylamines (1-substituted 2-phenylethylamines) 4 are obtained in high yields by a new, facile reaction of titanium amide complexes with aldehydes and benzylmagnesium chloride.