64890-04-6

Basic information

• Product Name: 3-Oxa-1-azabicyclo[3.1.0]hexan-2-one, 4,4,5-triphenyl-
• CAS NO: 64890-04-6
• Molecular Formula: C22H17NO2
• Molecular Weight: 327.382
• Mol File: 64890-04-6.mol

Chemical Properties

• CAS DataBase Reference: 3-Oxa-1-azabicyclo[3.1.0]hexan-2-one, 4,4,5-triphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxa-1-azabicyclo[3.1.0]hexan-2-one, 4,4,5-triphenyl-(64890-04-6)
• EPA Substance Registry System: 3-Oxa-1-azabicyclo[3.1.0]hexan-2-one, 4,4,5-triphenyl-(64890-04-6)

Safety Data

• Hazardous Substances Data: 64890-04-6(Hazardous Substances Data)

Upstream product

• 75-44-5 phosgene 
• 64889-89-0 diphenyl(2-phenyl-aziridin-2-yl)methanol 
• 1609-86-5 Tert-butyl isocyanate 
• 103-71-9 phenyl isocyanate 
• 119-51-7 1-phenyl-1,2-propanedione 2-oxime 
• 7474-15-9 1-hydroxy-1,1-diphenylpropan-2-one oxime 
• 102839-81-6 Carbonic acid diphenyl-(2-phenyl-aziridin-2-yl)-methyl ester ethyl ester 

Downstream Products

• 25683-83-4 2,3,3-triphenylacrylaldehyde 
• 89030-16-0 2,2,3-triphenyl-1-azabicyclo<1.1.0>butane 
• 119-61-9 benzophenone 
• 17282-99-4 3,4-diphenylquinoline 

Relevant articles and documents

Reaction of (2-ethyl-aziridin-2-yl)diphenyl methanol and diphenyl-(2-phenyl-aziridin-2-yl)methanol with phenyl and t-butyl isocyanates, phenyl isothiocyanate and thiophosgene

The reactions of aziridine alcohols with organic isocyanates, isothiocyanates and thiophosgene were described. It was found that the reactions with phenyl or t-butyl isocyanate give urea derivatives as major products, whereas the reaction with thiophosgene resulted in the formation of isothiocyanates derivatives. The mechanism of these reactions was proposed.

SYNTHESE PHOTOCHIMIQUE D'AZA-1 BICYCLOBUTANES

Aza-1 bicyclobutanes 2 are readily obtained by photolysis of carbamates 1. 1 are easily synthetised from 3.