65012-74-0 Usage
Uses
Used in Organic Synthesis:
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is used as a catalyst for a range of reactions in the field of organic synthesis. The rhodium center acts as a Lewis acid, which aids in the activation of substrates and promotes the desired chemical transformations.
Used in Hydrogenation Reactions:
In the Chemical Industry, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is used as a catalyst for hydrogenation reactions, facilitating the addition of hydrogen to various organic compounds.
Used in Hydroformylation Reactions:
Within the Chemical Industry, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is also utilized as a catalyst for hydroformylation reactions, which involve the conversion of alkenes to aldehydes in the presence of carbon monoxide and hydrogen.
Used in Cyclopropanation Reactions:
In the Chemical Industry, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is used as a catalyst for cyclopropanation reactions, where a molecule of a compound containing a carbon-carbon double bond reacts with a diazo compound to form a cyclopropane ring.
Used in Enantioselective Reactions:
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is used as a chiral catalyst for enantioselective reactions in the Pharmaceutical Industry. The chiral diphosphine ligand provides asymmetry to the catalyst, making it suitable for reactions that require the formation of specific enantiomers with high selectivity.
Check Digit Verification of cas no
The CAS Registry Mumber 65012-74-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,0,1 and 2 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 65012-74:
(7*6)+(6*5)+(5*0)+(4*1)+(3*2)+(2*7)+(1*4)=100
100 % 10 = 0
So 65012-74-0 is a valid CAS Registry Number.
InChI:InChI=1/C30H30P2.C7H8.ClHO4.Rh/c1-25(23-31(27-15-7-3-8-16-27)28-17-9-4-10-18-28)26(2)24-32(29-19-11-5-12-20-29)30-21-13-6-14-22-30;1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h3-26H,1-2H3;1-4,6-7H,5H2;(H,2,3,4,5);/p-1/t25-,26-;;;/m1.../s1/rC30H30P2Rh.C7H8.ClHO4/c1-23-24(2)30(32(27-19-11-5-12-20-27)28-21-13-6-14-22-28)33-29(23)31(25-15-7-3-8-16-25)26-17-9-4-10-18-26;1-2-7-4-3-6(1)5-7;2-1(3,4)5/h3-24,29-30H,1-2H3;1-4,6-7H,5H2;(H,2,3,4,5)/p-1/t23-,24-,29?,30?;;/m0../s1
65012-74-0Relevant academic research and scientific papers
A New Chiral Rhodium(I) Complex of (2R,3R)-2,3-Bis(diphenylphosphino)butane for Asymmetric Hydrogenations
Koettner, Johann,Greber, Gerd
, p. 2323 - 2325 (2007/10/02)
Rhodium(I) complexes of the new chiral ligand (2R,3R)-2,3-bis(diphenylphosphino)butane (4) - which is easily prepared from natural tartaric acid - hydrogenate α-(acylamino)acrylic acids to natural (S)-acylamino acids in high chemical (95-100percent) and optical (80-100percent) yields.
