650605-47-3Relevant academic research and scientific papers
Cationic vanadium(IV) complexes as efficient catalysts for nazarov cyclizations
Walz, Irene,Bertogg, Andreas,Togni, Antonio
, p. 2650 - 2658 (2008/02/08)
Vanadium(IV) species generated in situ from V(salen)Cl2 complexes (1) by reaction with 2 equiv. of AgSbF6 are effective catalysts for Nazarov cyclizations. Thus, dialkenyl ketones bearing α-ester groups are efficiently converted to c
Catalytic Asymmetric Nazarov Reactions Promoted by Chiral Lewis Acid Complexes
Aggarwal, Varinder K.,Belfield, Andrew J.
, p. 5075 - 5078 (2007/10/03)
(Equation presented) Divinyl ketones bearing α-ester or α-amide groups undergo Nazarov cyclizations to give cylopentenones using copper-bisoxazoline Lewis acid complexes with moderate to good ees.
