65064-78-0Relevant articles and documents
METHOD FOR PRODUCING FLUORINE-CONTAINING ETHER WITH HIGH PURITY
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Page/Page column 5, (2012/04/11)
The present invention provides a method for efficiently producing a highly pure fluoroether containing remarkably low concentration of a fluorine-containing alkyl alcohol. The method is suited for scale-up and specifically includes performing countercurrent separation of a crude solution of fluoroether including a fluorine-containing alkyl alcohol as an impurity using water.
Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis
Il'in,Il'in,Bakhmutov,Furin,Pokrovskii
, p. 405 - 418 (2008/02/02)
Perfluoroolefins react with isopropyl alcohol under the conditions of radical initiation to form partially fluorinated aliphatic alcohols. The reactions of these alcohols with hexafluoropropylene and compounds containing labile halogen atoms (in particular, with allyl bromide and epichlorohydrin) were studied.
Synthesis and use of partially fluorinated dialkyl ethers derived from hexafluoropropylene
Il'in,Bakhmutov,Ivanova,Furin,Tolstikova,Sukhinin
, p. 98 - 101 (2007/10/03)
A procedure was developed for preparing partially fluorinated dialkyl ethers by the reaction of hexafluoropropylene with aliphatic and polyfluorinated alcohols in the presence of KOH. On treatment with concentrated sulfuric acid, these ethers form alkyl esters of acids, and on treatment with KOH, alkenyl ethers.