651-93-4Relevant articles and documents
A Synthesis of Novel Perfluorodienes
Briscoe, Mark W.,Chambers, Richard D.,Mullins, Steven J.,Nakamura, Takayuki,Drakesmith, Frederick G.
, p. 1127 - 1128 (1990)
Oligomers of perfluoroalkenes are converted to dienes in good yields, using sodium amalgam; these dienes are highly susceptible to nucleophilic attack and can be excellent sources of heterocycles.
CYCLIC COMPOUNDS FROM PERFLUORO-3,4-DIMETHYLHEXA-2,4-DIENE
Chambers, R. D.,Mullins, S. J.,Drakesmith, F. G.
, p. 258 (1991)
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Fluorinated di-enes
Chambers, R. D.,Vaughan, J. F. S.,Mullins, S. J.,Nakamura, T.,Roche, A. J.
, p. 231 - 234 (1995)
Fluorinated di-enes may be obtained by the defluorination of some oligomers of F-alkenes and -cycloalkenes using tetrakis(dimethylamino)ethene.These di-enes are very susceptible to nucleophilic attack.Nucleophilic epoxidation of (4) gives a new diepoxide which undergoes a novel ring-opening reaction.Di-ene (4) forms cyclopentadienylide derivatives with di-functional carbon nucleophiles and a cyclopentadienylide salt (17) is obtained in a remarkable 'one-pot' reaction from hexachlorobutadiene. (4) (17) - Keywords: Fluorinated di-enes; Tetrakis(dimethylamino)ethene; Defluorination
Wiebe et al.
, p. 2721 (1972)