39091-73-1

Basic information

• Product Name: 1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene
• Synonyms: 1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene
• CAS NO: 39091-73-1
• Molecular Formula: C₈F₁₂S
• Molecular Weight: 356.13
• Mol File: 39091-73-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene(39091-73-1)
• EPA Substance Registry System: 1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene(39091-73-1)

Safety Data

• Hazardous Substances Data: 39091-73-1(Hazardous Substances Data)

Usage

Molecular structure

1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene consists of a five-membered sulfur-containing ring with four trifluoromethyl groups attached to it.

Synthetic organic compound

It is a man-made chemical substance, created through artificial synthesis methods.

Highly fluorinated molecule

The presence of four trifluoromethyl groups indicates a high degree of fluorination, which can influence the compound's properties and reactivity.

Potential applications

1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene has potential uses in the fields of organic chemistry and materials science, such as modifying reactivity and selectivity in chemical reactions, and enhancing material properties.

Building block for synthesis

Due to its unique structure and fluorinated groups, 1,2,3,4-Tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene can be used as a starting material for creating novel fluorinated compounds with various applications in industry and research.

Upstream product

• 651-93-4 tetrakis(trifluoromethyl)thiophene 
• 692-50-2 hexafluoro-2-butyne 

Downstream Products

• 64724-55-6 8-cyclohexyl-1,2,4,5-tetrakis-trifluoromethyl-(1rH,2tH,4tH,5cH)-3-thia-6,7,8-triaza-tricyclo[3.3.0.0^2,4]oct-6-ene 
• 651-93-4 tetrakis(trifluoromethyl)thiophene 
• 73688-06-9 4-cyclohexyl-1,5,6,7-tetrakis(trifluoromethyl)-2,3,4-triazabicyclo<3.2.0>hepta-2.6-diene 
• 73688-39-8 C₃₂H₂₆F₁₂N₃P 
• 73688-36-5 Cyclohexyl-[(Z)-4-diazo-5,5,5-trifluoro-1,2,3-tris-trifluoromethyl-pent-2-en-(Z)-ylidene]-amine 
• 73688-45-6 Cyclohexyl-[2,2,2-trifluoro-1-(2,3,4-tris-trifluoromethyl-2H-thiet-2-yl)-eth-(E)-ylidene]-amine 
• 73688-40-1 N-cyclohexyl-2,3,4,5-tetrakis(trifluoromethyl)pyrrole 
• 73688-42-3 Cyclohexyl-[2,2,2-trifluoro-1-(1,2,3-tris-trifluoromethyl-cycloprop-2-enyl)-eth-(Z)-ylidene]-amine 
• 64724-54-5 8-phenyl-1,2,4,5-tetrakis-trifluoromethyl-(1rH,2tH,4tH,5cH)-3-thia-6,7,8-triaza-tricyclo[3.3.0.0^2,4]oct-6-ene 
• 73679-97-7 N-phenyl-2,3,4,5-tetrakis(trifluoromethyl)pyrrole 

Relevant articles and documents

PHOTOISOMERISATION OF BIS(TRIFLUOROMETHYL)THIOPHENES

The photolysis of 2,3-bis(trifluoromethyl)thiophene gave an equilibrium mixture of 2,3- and 3,4-bis(trifluoromethyl)Dewar thiophenes, while that of 2,5-bis(trifluoromethyl)thiophene gave 2,4-bis(trifluoromethyl)thiophene, which seemed to be formed through an intermediate other than the Dewar form.

Thiirene formation in the reactions of sulfur atoms with alkynes

The gas phase reactions of S(1D2) and S(3PJ) atoms with alkynes have been studied by photolyzing COS in the presence of CHCH, CF3CCH, and CF3CCCF3.In the reactions with CHCH, CS2, benzene, and thiophene were formed; with CF3CCH, eight products found with disubstituted thiophenes and trisubstituted benzenes as the major products.In the case of CF3CCCF3, only perfluorotetramethylthiophene was detected at low conversion but at long photolysis several new products were observed.Many of the reaction products characterized here have not been reported before.The formation and distribution of the reaction products could be rationalized by an overall mechanism in which the formation of the highly reactive primary adducts, thiirene and thioformylmethylene, is followed by bimolecular reactions yielding the principal end products.The formation of minor products could be explained by secondary photoisomerizations, secondary photolysis, and by secondary decompositions and the secondary reactions of sulfur atoms with primary products.