651293-91-3

Basic information

• Product Name: C₄₉H₆₅NO₁₃Si
• Synonyms: C₄₉H₆₅NO₁₃Si
• CAS NO: 651293-91-3
• Molecular Weight: 904.14
• Mol File: 651293-91-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₉H₆₅NO₁₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₉H₆₅NO₁₃Si(651293-91-3)
• EPA Substance Registry System: C₄₉H₆₅NO₁₃Si(651293-91-3)

Safety Data

• Hazardous Substances Data: 651293-91-3(Hazardous Substances Data)

Upstream product

• 994-30-9 triethylsilyl chloride 
• 76429-85-1 10β-deacetylcephalomannine 
• 71610-00-9 cephalomannine 

Relevant articles and documents

The Reductive Fragmentation of 7-Hydroxy-9,10-dioxotaxoids

The retro-aldol reductive fragmentation of different structural types of 7-hydroxy-9,10-dioxotaxoids was investigated, showing that the reaction is typical of taxanes and requires cerium(III) promotion with NaBH4 in protic medium and alkylboron (aluminium) hydrides in aprotic solvents. The resulting 7,8-seco-taxanes are key intermediates for the synthesis of a novel class of anticancer taxanes endowed with a unique pattern of in vivo biological activity. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.