65212-14-8Relevant academic research and scientific papers
Reactions of acyl chlorides with LiAlHSeH. Preparation of diacyl selenides, diacyl diselenides, selenocarboxylates and cyclic selenoanhydrides
Koketsu, Mamoru,Nada, Futoshi,Hiramatsu, Sohma,Ishihara, Hideharu
, p. 737 - 740 (2002)
Various diacyl selenides, diacyl diselenides and selenocarboxylates were synthesized by reaction of several acyl chlorides with LiAlHSeH. Reaction of diacyl chloride with LiAlHSeH afforded cyclic selenoanhydrides. In the 77Se NMR spectra, we fo
Identifying reactive organo-selenium precursors in the synthesis of CdSe nanoplatelets
Riedinger, Andreas,Mule, Aniket S.,Knüsel, Philippe N.,Ott, Florian D.,Rossinelli, Aurelio A.,Norris, David J.
supporting information, p. 11789 - 11792 (2018/11/27)
In the synthesis of CdSe nanoplatelets, the selenium-to-selenide reduction pathway is unknown. We study solvent-free growth of CdSe nanoplatelets and identify bis(acyl) selenides as key reactive intermediates. Based on our findings, we prepare a series of bis(acyl) selenides that provide useful precursors with tailored reactivity for liquid-phase syntheses of nanoplatelets.
Organoselenosilane-mediated selective mild access to selenolesters, selenoanhydrides and diacyl diselenides
Capperucci, Antonella,Deglinnocenti, Alessandro,Tiberi, Caterina
experimental part, p. 2248 - 2252 (2011/10/31)
Reaction of acyl chlorides with phenylselenotrimethyl-silane promoted by TBAF afforded a mild general access to selenolesters in good yields. When acyl chlorides were reacted with bis(trimethylsilyl)selenide (HMDSS) in 2:1 or 1:1 ratio a selective entry t
Selenium transfer reaction of primary selenoamides: A novel method for the synthesis of diacylselenides from acyl chlorides
Zhao, Hua-Rong,Zhao, Xin-Jian,Huang, Xian
, p. 3383 - 3387 (2007/10/03)
Diacyl selenides were afford in excent yields by reaction of primary selenoamides with acyl chlorides in chloroform. A possible mechanism is discussed.
