65285-58-7

Usage

InChI:InChI=1/C14H13ClN2O/c15-8-1-3-12-10(7-8)9-5-6-16-11-2-4-13(18)17(12)14(9)11/h1,3,7,11,16H,2,4-6H2

Upstream product

• 859163-75-0 6-chloro-1-vinyl-2,3,4,9-tetrahydro-1H-β-carboline 
• 859163-76-1 6-chloro-2-tert-butyloxycarbonyl-1-vinyl-2,3,4,9-tetrahydro-1H-β-carboline 
• 859163-70-5 N-[2-(5-chloro-1H-indol-3-yl)ethyl]-4-nitrobenzenesulfonylamide 
• 859163-77-2 6-chloro-1-(2-methoxycarbonylvinyl)-1,3,4,9-tetrahydro-β-carboline-2-carboxylic acid tert-butyl ester 
• 859163-78-3 6-chloro-1-(2-methoxycarbonylethyl)-1,3,4,9-tetrahydro-β-carboline-2-carboxylic acid tert-butyl ester 
• 859163-72-7 6-chloro-2-(4-nitrobenzenesulfonyl)-1-vinyl-2,3,4,9-tetrahydro-1H-β-carboline 
• 859163-71-6 N-(1-benzyloxyallyl)-N-[2-(5-chloro-1H-indol-3-yl)ethyl]-4-nitrobenzenesulfonylamide 
• 827-01-0 5-chloro-1H-indole-3-carboxaldehyde 
• 3764-94-1 5-chlorotryptamine 
• 98993-95-4 5-chloro-3-(2-nitrovinyl)indole 
• 859163-79-4 10-chloro-6-oxo-1,2,3a,4,5,6-hexahydroindolo[3,2,1-de][1,5]naphthyridine-3-carboxylic acid tert-butyl ester 

Relevant academic research and scientific papers

Catalytic N-sulfonyliminium ion-mediated cyclizations to α-vinyl-substituted isoquinolines and β-carbolines and applications in metathesis

Catalytic Sn(OTf)2-induced cyclization of linear, aryl-containing allylic N,O-acetals produced vinyl-substituted tetrahydroisoquinolines and tetrahydro-1H-β-carbolines. The usefulness of the vinyl moiety in the resulting products was demonstrated via the synthesis of various key building blocks for alkaloid structures. The α-vinyl moiety was utilized in a [2,3] sigmatropic rearrangement, in ring-closing metathesis and a cross-metathesis-based synthesis of vincantril, an antianoxia agent, and a synthetic member of the vincamine type natural products.