65288-09-7Relevant academic research and scientific papers
Lipase-mediated diastereoselective and enantioselective acetylations of 3-substituted cyclohexanols
Tanikaga, Rikuhei,Morita, Akira
, p. 635 - 638 (2007/10/03)
Lipase-mediated acetylation of four diastereomeric and enantiomeric isomers of 3-substituted cyclohexanols 2 has led to an efficient resolution to provide a single stereoisomer, (1R,3S)-cyclohexyl acetate (1R,3S)-3 in a high enantiomeric excess.
The Strain Limit in Intramolecular Nucleophilic Substitution
Jeffery, Stephen M.,Stirling, Charles J. M.
, p. 1617 - 1624 (2007/10/02)
Kinetics and products of reactions of sulfonyl-stabilised carbanions bearing ω-leaving groups have been examined.The intention was to explore the upper limit of strain that can be tolerated for intramolecular nucleophilic substitution in these systems and
