65417-74-5

Basic information

• Product Name: 6-BROMO-1,3-BENZODIOXOLE-5-CARBALDEHYDE OXIME
• Synonyms: 6-BROMO-3,4-METHYLENEDIOXYBENZALDEHYDE OXIME;6-BROMO-1,3-BENZODIOXOLE-5-CARBALDEHYDE OXIME;(E)-N-[(6-bromo-2H-1,3-benzodioxol-5-yl)methylidene]hydroxylamine
• CAS NO: 65417-74-5
• Molecular Formula: C₈H₆BrNO₃
• Molecular Weight: 244.04
• Mol File: 65417-74-5.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6-BROMO-1,3-BENZODIOXOLE-5-CARBALDEHYDE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 6-BROMO-1,3-BENZODIOXOLE-5-CARBALDEHYDE OXIME(65417-74-5)
• EPA Substance Registry System: 6-BROMO-1,3-BENZODIOXOLE-5-CARBALDEHYDE OXIME(65417-74-5)

Safety Data

• Hazardous Substances Data: 65417-74-5(Hazardous Substances Data)

Upstream product

• 120-57-0 piperonal 
• 15930-53-7 6-bromo-3,4-methylenedioxybenzaldehyde 

Downstream Products

• 67496-29-1 1-bromo-6-aminomethyl-3,4-(methylenedioxy)-benzene 
• 888316-54-9 methyl (1'R,4'S)-2-(4'-benzoyloxy-2'-cyclohexen-1'-yl)-2-N-[6''-bromo-3'',4''-(methylene-dioxy)benzyl]carbamoylacetate 
• 6871-58-5 (+)-γ-lycorane 
• 18034-03-2 nornitidine 
• 226570-99-6 N-(6-bromo-3,4-dimethoxybenzyl)-N-(cyclohex-1-enyl)-2,2,2-trichloroacetamide 
• 63814-03-9 1,2,3,3a,4,5,12b,12c-octahydro-7H-1,3-benzodioxolo[5,6-c]pyrrolo[3,2,1-ij]quinoline 

Relevant articles and documents

Palladium-Catalyzed α-Arylation of Silylenol Ethers in the Synthesis of Isoquinolines and Phenanthridines

A diverse array of isoquinolines and phenanthridines have been accessed by developing a two-step, one-pot method constituting regioselective palladium-catalyzed Kuwajima-Urabe α-arylation of silylenol ethers and acid-mediated deprotection, annulation, and aromatization. Structural diversity in the silylenol ethers leads to three different classes of isoquinolines and phenanthridines from which related natural products can be derived. The synthetic utility of this method by the quick assembly of the natural product trispheridine is also demonstrated.

Catalytic asymmetric transformations with fine-tunable biphenol-based monodentate ligands

A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol have been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation and Rh-catalyzed asymmetric hydrogenation.