65439-56-7Relevant academic research and scientific papers
Ni(II) Tol-BINAP-catalyzed enantioselective orthoester alkylations of N-acylthiazolidinethiones
Evans, David A.,Thomson, Began J.
, p. 10506 - 10507 (2005)
The development of a Ni(II) (S)-Tol-BINAP-catalyzed enantioselective alkylation of N-acylthiazolidinethiones with trimethyl orthoformate is described. The reaction is general with respect to the thiazolidinethione, providing the desired adducts in good to
Efficient acylation of alcohols with acylthiazolidine-2-thiones and cesium fluoride
Yamada, M.,Yahiro, S.,Yamano, T.,Nakatani, Y.,Ourisson, G.
, p. 824 - 829 (2007/10/02)
Primary alcohols are acylated in good yield under almost neutral conditions with 3-acylthiazolidine-2-thiones and cesium fluoride.For secondary alcohols, the yield is improved by the addition of zinc bromide. t-Butanol is not acylated.
