6559-34-8Relevant articles and documents
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Baldwin,Brown
, p. 3099,3105 (1969)
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Vers la synthese totale de la d,l-desosamine. Formation du carbon anomere au moyen de PhSeBr
Berube, Gervais,Luce, Eric,Jankowski, Krzysztof
, p. 109 - 111 (2007/10/02)
Reaction of phenylselenyl bromide with dihydropyrans in the presence of methanol, followed by oxidative elimination, leads to α,β-unsaturated acetals.This method, which constitutes a new way for generating an anomeric center in the total synthesis of hexopyranose derivatives, has been applied towards the synthesis of methyl 3,4,6-trideoxy-3-dimethylamino-D,L-xylo hexopyranoside (methyl D,L-desosamide).