656224-05-4

Basic information

• Product Name: dimethyl 2,6-anhydro-3,4-di-O-benzoyl-5-O-mesyl-D-glycero-L-gluco-heptarate
• Synonyms: dimethyl 2,6-anhydro-3,4-di-O-benzoyl-5-O-mesyl-D-glycero-L-gluco-heptarate
• CAS NO: 656224-05-4
• Molecular Weight: 536.513
• Mol File: 656224-05-4.mol

Chemical Properties

• CAS DataBase Reference: dimethyl 2,6-anhydro-3,4-di-O-benzoyl-5-O-mesyl-D-glycero-L-gluco-heptarate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2,6-anhydro-3,4-di-O-benzoyl-5-O-mesyl-D-glycero-L-gluco-heptarate(656224-05-4)
• EPA Substance Registry System: dimethyl 2,6-anhydro-3,4-di-O-benzoyl-5-O-mesyl-D-glycero-L-gluco-heptarate(656224-05-4)

Safety Data

• Hazardous Substances Data: 656224-05-4(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 124-63-0 methanesulfonyl chloride 
• 656224-02-1 dimethyl 2,6-anhydro-D-glycero-L-gluco-heptarate 
• 14125-78-1 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-lyxo-hex-1-enitol 
• 79292-17-4 methyl 2,6-anhydro-D-glycero-L-gluco-heptonate 
• 78393-35-8 3,4,5,7-Tetra-O-acetyl-2,6-anhydro-D-glycero-L-gluco-heptonamide 

Downstream Products

• 58262-15-0 dimethyl 4,5-di-O-benzoyl-2,6-anhydro-3-deoxy-D-xylo-hept-2-enarate 

Relevant articles and documents

(-)-Daucic Acid: Revision of Configuration, Synthesis, and Biosynthetic Implications

The synthesis of dihydropyrans with the D-xylo (1), D-ribo, L-arabino, and D-lyxo (2) configuration by one-carbon-atom homologation of D-mannose or D-galactose, terminal oxidation, and directed β elimination revealed (-)-daucic acid isolated from carrots

(-)-Daucic acid: Proof of D-lyxo configuration, synthesis of its D-ribo, D-xylo, L-arabino and L-lyxo analogs, and biosynthetic implications

The dimethyl esters of the 2,6-anhydro-3-deoxy-hept-2-enaric acids with D-xylo, D-lyxo, L-arabino, L-lyxo- and D-ribo-configuration were synthesized from D-galactose and D-mannose, respectively, and further characterized by their di-O-acetyl and di-O-benz