65693-19-8Relevant academic research and scientific papers
Regio- and Stero-selective Desulphurizative γ-Substitution of α-Substituted β-Methylallyl Sulphoxides and Sulphones with Lithium Dialkylcuprates providing Trisubstituted Olefins
Masaki, Yukio,Sakuma, Kazuhiko,Kaji, Kenji
, p. 1170 - 1176 (2007/10/02)
α-Substituted β-methylallyl sulphoxides (2) and sulphones (3) undergo regio- and stereo-selective desulphurizative γ-substitution by the action of lithium dialkylcuprates in ether.The reaction provides a new method for the synthesis of trisubstituted E-ol
