65751-66-8

Upstream product

• 2771-55-3 2,3,4-Tri-O-benzyl-D-mannopyranose 
• 76679-39-5 [(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl trifluoromethanesulfonate 
• 81005-45-0 2,3,4-Tri-O-benzyl-(R-2,3-dihydroxypropyl)-β-D-mannopyranosid 
• 77-76-9 2,2-dimethoxy-propane 
• 22323-82-6 (S)-(+)-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol 
• 67-64-1 acetone 

Downstream Products

• 81005-45-0 2,3,4-Tri-O-benzyl-(R-2,3-dihydroxypropyl)-β-D-mannopyranosid 
• 76227-34-4 Toluene-4-sulfonic acid (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-tetrahydro-pyran-2-ylmethyl ester 
• 221697-43-4 Phosphoric acid (S)-2-azido-3-hydroxy-propyl ester 2-cyano-ethyl ester (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-tetrahydro-pyran-2-ylmethyl ester 
• 221697-44-5 {2-[((S)-2-Azido-3-{(2-cyano-ethoxy)-[(2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-tetrahydro-pyran-2-ylmethoxy]-phosphoryloxy}-propoxy)-(2-cyano-ethoxy)-phosphoryloxy]-ethyl}-trimethyl-ammonium 
• 76227-36-6 bis-<3-O-(2,3,4-tri-O-benzyl-6-deoxy-α-D-glucopyranosyl)-1,2-O-isopropylidene-L-glycerol>-6,6-disulphide 
• 76227-37-7 bis-<3-O-(2,3,4-tri-O-benzyl-6-deoxy-α-D-glucopyranosyl)-L-glycerol>-6,6-disulphide 
• 76234-88-3 Thioacetic acid S-[(2S,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-tetrahydro-pyran-2-ylmethyl] ester 
• 76227-35-5 [(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-tetrahydro-pyran-2-yl]-methanethiol 

Relevant academic research and scientific papers

Synthesis and Absolute Configuration of a Novel Aminoglycoglycerolipid, Species-Specific Major Immunodeterminant of Mycoplasma fermentans

In order to determine the absolute configuration of a novel aminoglycoglycerolipid isolated from Mycoplasma fermentans, the possible two diastereomers were stereoselectively synthesized by using (S)- and (R)-glycidols as the key building block. Their 1H-1H-cosy spectra compared with those of the natural product allowed us to determine the absolute configuration of the glycolipid. - Keywords: amino-alcohols; glycolipids; immunodeficiency; phospholipids; phosphoramidites

O-Alkylierung am anomeren Zentrum, 4. 1-O-Alkylierung von D-Mannofuranose und D-Mannopyranose

From 1-O-metallated 2,3;5,6-di-O-isopropylidene-D-mannose (1) and strong alkylating agents (triflates) β-D-mannofuranosides were obtained, addition of crown ether resulted in α-D-mannofuranoside formation.From the 6-O-unprotected D-mannose 7 a similar ste