65797-29-7Relevant academic research and scientific papers
Applications of α-phosphonovinyl tosylates in the synthesis of α-arylethenylphosphonates via suzuki-miyaura cross-coupling reactions
Fang, Yewen,Li, Jinjian,Wu, Rong,Fang, Jianghua,Zhang, Li,Yuan, Meijuan,Li, Ruifeng,Jin, Xiaoping
, p. 798 - 801 (2015)
It has been demonstrated for the first time that α-phosphonovinyl tosylates could efficiently couple with a range of arylboronic acids to access α-arylethenylphosphonates. The unprecedented procedure exhibits excellent functional group tolerance, giving the terminal vinylphosphonates in good to excellent isolated yields (60-99%) under mild reaction conditions.
Metal-free diimide reduction of alkenylphosphonates: simple and efficient protocol for the synthesis of α-substituted ethylphosphonates
Fang, Yewen,Yuan, Meijuan,Jin, Xiaoping,Zhang, Li,Li, Ruifeng,Yang, Shaoshuai,Fang, Mei
supporting information, p. 1368 - 1371 (2018/03/23)
A simple and straightforward method for the synthesis of α-substituted ethylphosphonates via diimide reduction strategy is described. With K3PO4 or Na2CO3 as the basic additive, a range of terminal alkenylphosph
