65818-13-5Relevant academic research and scientific papers
One-step transformation of ammonium dialkyl phosphoroselenoates into dialkyl phosphoramidates
Mielniczak, Grazyna,Lopusinski, Andrzej
, p. 121 - 127 (2003)
Ammonium dialkyl phosphoroselenoates are directly converted into the dialkyl phosphoramidates by iodosobenzene and iodoxybenzene. The inversion of configuration at the phosphorus atom, using model diastereoisomeric ammonium cis- and trans-2-oxo-2-seleno-4-methyl-1,3,2-dioxaphosphinan system, was observed. The mechanistic scheme of this transformation is discussed.
