2651-89-0Relevant articles and documents
4,5-Bis(diphenylphosphanyl)-1,2,3-triazole and its conversion to 1,1,3,3,-tetraphenyl-1,3-diphospha-2,4,5,6-tetraazapentalene
Trofimenko, Swiatoslaw,Rheingold, Arnold L.,Incarvito, Christopher D.
, p. 3506 - 3509 (2007/10/03)
Towards a new family of ligands: The synthesis of the ligand HLT (depicted left) is described. Although H LTappears to be a simple chelating diphosphane, the tiazole proton can be removed with a base to produce an anionic diphosphane. Thus HLT
Reaction of three-coordinate phosphorus compounds with organophosphorus pseudohalogens. Part 4. The mechanism of interaction between bis(phosphinoyl) diselenides [R1R2P(O)Se]2 with three-coordinate phosphorus compounds
Krawczyk, Ewa,Skowronnska, Aleksandra,Michalski, Jan
, p. 1135 - 1140 (2007/10/03)
The reaction of bis(phosphinoyl) diselenides R1R2P(O)Se-SeP(O)R1R2 1 with P(III) compounds has been investigated and its mechanistic features have been elucidated by variable temperature 31P NMR spectroscopy. These studies show that in most cases phosphonium intermediates [>P(O)-Se-P+-O-P(Se)P(Se)-O-P+-O-P(Se)a phosphorane intermediate is observed. In the isomerization 7→10 and 13→16 the pathway of decomposition (deselenization, deoxygenation or dealkylation) to give stable end products is influenced by electronic and steric factors.