85687-32-7

Upstream product

• 85687-30-5 methyl 4-O-benzoyl-6-bromo-2,3,6-trideoxy-3-C-methyl-3-(trifluoroacetamido)-α-D-ribo-hexopyranoside 
• 98758-29-3 methyl 3-amino-4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-α-D-ribo-hexopyranoside 
• 85687-29-2 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-3-trifluoroacetamido-α-D-ribo-hexopyranoside 
• 98758-31-7 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-3-(trifluoroacetamido)-α-D-ribo-hexopyranoside 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 85687-31-6 methyl 4-O-benzoyl-2,3,6-trideoxy-6-iodo-3-C-methyl-3-trifluoroacetamido-α-D-ribo-hexopyranoside 
• 95086-98-9 methyl 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-D-erythro-hex-5-enopyranoside 
• 65827-66-9 (4aR,6S,8aS)-6-Methoxy-8-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ylamine 
• 98758-27-1 methyl 3-C-(azidomethyl)-4,6-O-benzylidene-2-deoxy-3-O-methylsulphonyl-α-D-arabino-hexopyranoside 
• 98818-14-5 methyl-3-C-(azidomethyl)-4,6-O-benzylidene-2-deoxy-α-D-arabino-hexopyranoside 
• 13264-05-6 methyl 3,3¹-anhydro-<4,6-O-benzylidene-2-deoxy-3-C-(hydroxymethyl)-α-D-arabino-hexopyranoside> 
• 149353-42-4 methyl 4,6-O-benzylidene-2,3-dideoxy-3-(O-benzylhydroxyamino)-3-C-methyl-α-D-ribo-hexopyranoside 

Relevant academic research and scientific papers

A New Stereoselective Route to Branched-Chain Nitro and Amino Sugars: Synthesis of Both Enantiomers of Decilonitrose and Avidinosamine

Short, efficient, and highly diastereoselective syntheses of the title carbohydrates (15, 21, and 22), components of new anthracycline antibiotics, on a gram scale from readily available keto sugar precursors 6 and 17 are described.The syntheses feature t

Branched-chain Sugars. Part 18. Syntheses of D-Rubranitrose (2,3,6-Trideoxy-3-C-methyl-4-O-methyl-3-nitro-D-xylo-hexopyranose) and a Derivative of D-Kijanose (2,3,4,6-Tetradeoxy-4-methoxycarbonylamino-3-methyl-3-nitro-α-D-xylo-hexopyranose)

D-Rubranitrose (2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitro-D-xylo-hexopyranose) (22), a constituent of the antibiotic rubradirin, has been synthesized from methyl 3,31-anhydro-4,6-O-benzylidene-2-deoxy-3-C-(hydroxymethyl)-α-D-arabino-hexopyr

SYNTHESIS AND ANTITUMOR ACTIVITY OF 3'-C-METHYL-DAUNORUBICIN

Reaction of 1,5-anhydro-4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-L-lyxo-hex-1-enitol with daunomycinone in the presence of anhydrous toluene-p-sulfonic acid in benzene, followed by removal of the N- and O-protecting groups under mild con