6588-35-8Relevant articles and documents
Unexpected Opposite Stereochemistries and Different Mechanisms of Nucleophilic Substitution Reactions of Homochiral tert-Butylphenylthiophosphinoyl Chloride and Bromide
Omelanczuk, Jan,Mikolajczyk, Marian
, p. 2223 - 2224 (2007/10/02)
Reactions of ethylmercapto (ethylsulfanyl) anion with homochiral (+)-(S)-tert-butylphenylphosphinochloridothionate 2 and (-)-(S)-tert-butylphenylphosphinobromidothionate 3 proceed with inversion and retention at phosphorus, respectively, as a consequence