65885-20-3Relevant academic research and scientific papers
Action d'organometalliques fonctionnels sur des gem-aminoethers et des sels d'immonium. I. Synthese d'amines α- ou β-fonctionnelles difficilement accessibles par reaction de Mannich
Courtois, Gilles,Miginiac, Philippe
, p. 395 - 400 (2007/10/02)
Some α- or β-functional amines which are difficult to obtain by Mannich reaction can be easily prepared from organomagnesium or organozinc functional derivatives and gem-aminoethers or immonium salts.
Directed Diastereotopic Lithiation of β-Heterosubstituted Alkyl Sulfones
Eisch, John J.,Galle, James E.
, p. 4534 - 4536 (2007/10/02)
The directed, highly diastereoselective lithiation of β-aminoalkyl sulfones by organolithium reagents has been shown capable of producing either diastereomeric lithio derivative with greater than 90percent selectivity, depending upon the type of amino group.
