65926-75-2Relevant academic research and scientific papers
Preparation of acetals from aldehydes and alcohols under basic conditions
Grabowski, Jakub,Granda, Jaros?aw M.,Jurczak, Janusz
supporting information, p. 3114 - 3120 (2018/05/17)
A new, simple protocol for the synthesis of acetals under basic conditions from non-enolizable aldehydes and alcohols has been reported. Such reactivity is facilitated by a sodium alkoxide along with a corresponding trifluoroacetate ester, utilizing formation of sodium trifluoroacetate as a driving force for acetal formation. The usefulness of this protocol is demonstrated by its orthogonality with various acid-sensitive protecting groups and by good compatibility with functional groups, delivering synthetically useful acetals complementarily to the synthesis under acidic conditions from aldehydes and alcohols.
Selective Single-Step Oxidation of Amine to Cross-Azo Compounds with an Unhampered Primary Benzyl Alcohol Functionality
Sarkar, Sayan,Sarkar, Piyali,Ghosh, Pradyut
supporting information, p. 6725 - 6729 (2018/10/25)
This is the first report of a single-step synthesis of primary benzyl alcohol containing different cross-azo compounds (14 examples) by Cu(II) in the presence of a newly synthesized amino-ether heteroditopic macrobicycle cage. Interestingly, even with ext
A photochromic agonist of AMPA receptors
Stawski, Philipp,Sumser, Martin,Trauner, Dirk
supporting information; experimental part, p. 5748 - 5751 (2012/08/14)
Light switch: A photochromic agonist ATA-3 (see scheme) of AMPA receptors, arguably the most important class of ionotropic glutamate receptors, is shown to be subtype selective, activates the AMPA receptor GluA2 in the dark, and is quickly turned off when
Synthesis and biological evaluation of triazole analogues of antillatoxin
Goto, Ryosuke,Okura, Ken,Sakazaki, Hayato,Sugawara, Tatsuya,Matsuoka, Shigeru,Inoue, Masayuki
experimental part, p. 6659 - 6672 (2011/10/01)
Antillatoxin 1, a cyclic lipopeptide, is known as an activator of voltage-gated sodium channels and exhibits potent neurotoxicity toward Neuro 2a mouse neuroblastoma cells. To investigate the biological effects of the side-chain structures at C5 and C5′ i
Bis(azobenzene)-based photoswitchable, prochiral, Cα- tetrasubstituted α-amino acids for nanomaterials applications
Fatas, Paola,Longo, Edoardo,Rastrelli, Federico,Crisma, Marco,Toniolo, Claudio,Jimenez, Ana I.,Cativiela, Carlos,Moretto, Alessandro
supporting information; experimental part, p. 12606 - 12611 (2011/12/21)
Light-driven chirality: Sequential light-driven isomerization of prochiral, bis(azobenzene)-containing amino acids results in the formation of chiral entities that have been characterized by different techniques. Metal nanoparticles conjugated with these amino acids retain the photoswitching properties and show conformation-dependent magnetic susceptibility that can be reversibly controlled by irradiation (see figure).
