66049-46-5Relevant academic research and scientific papers
Preparation of N-arylamines from 2-oxo-7-azobicyclo[4.1.0]heptanes
Barros, M. Teresa,Dey, Suvendu S.,Maycock, Christopher D.,Rodrigues, Paula
supporting information; scheme or table, p. 6263 - 6268 (2012/08/28)
A wide range of N-phenylated secondary amines were prepared directly from 2-oxo-7-azobicyclo[4.1.0]heptanes using 4-nitrobenzoic acid as acid catalyst. The intermediate enol esters could also be isolated under similar conditions. A catalytic cycle is proposed.
Selectivity in 1,3-Dipolar cycloadditions of β-substituted captodative olefins - An experimental and DFT transition state study
Herrera, Rafael,Mendoza, Jorge A.,Morales, Miguel A.,Mendez, Francisco,Jimenez-Vazquez, Hugo A.,Delgado, Francisco,Tamariz, Joaquin
, p. 2352 - 2364 (2008/02/08)
Captodative olefins 1-acetylvinyl carboxylates substituted with alkyl groups at the β position, 12, strongly modified the regioselectivity of 1,3-dipolar cycloadditions with respect to the behavior observed for their unsubstituted analogs, 1. When the rea
