66101-30-2

Upstream product

• 109-99-9 tetrahydrofuran 
• 25541-58-6 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-erythro-hex-2-enopyranoside 
• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 72523-26-3 methyl 2,3-anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside 
• 18604-56-3 methyl 2-O-acetyl-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-glucopyranoside 

Downstream Products

• 6752-52-9 (2R,6S,8S)-6-Methoxy-8-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol 

Relevant academic research and scientific papers

DENITRATION OF CARBOHYDRATE α-NITROEPOXIDES BY NUCLEOPHILES

Several nucleophiles were separately treated with methyl and phenyl 2,3-anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside, to give 2-substituted aldos-3-ulose derivatives.In the latter case, the subsequent β-elimination of the aglyconic phenyl

PHOTOREACTION OF METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-NITRO-β-D-erythro-HEX-2-ENOPYRANOSIDE WITH 1,3-DIOXOLANE AND TETRAHYDROFURAN

Irradiation of the title compound in 1,3-dioxolane and in tetrahydrofuran respectively afforded the D-gluco and D-manno isomers having 1,3-dioxolan-2-yl and terahydrofuran-2-yl group at C-2, besides the glycosid-3-ulose and nitro alcohol; in the later case, the dimer was also isolated.